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质量水平
检测方案
98%
形式
powder
mp
711 °C (lit.)
密度
3.72 g/mL at 25 °C (lit.)
SMILES字符串
Br[Mg]Br
InChI
1S/2BrH.Mg/h2*1H;/q;;+2/p-2
InChI key
OTCKOJUMXQWKQG-UHFFFAOYSA-L
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应用
溴化镁(MgBr2)可用作以下应用的催化剂：
- 醇（伯醇和仲醇）与酸酐的乙酰化和苯甲酰化。
- 合成二氢嘧啶酮、三氟甲基萘、取代1,2,3,4四氢嘧啶-2-酮。
- 通过Baylis-Hillman烯烃加氢，制备Aldol衍生物。
- SEM（2-(三甲基硅烷基)乙氧甲基)醚基脱保护。
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Magnesium bromide mediated highly diastereoselective heterogeneous hydrogenation of olefins
Bouzide, Abderrahim
Organic Letters, 4(8), 1347-1350 (2002)
Synthesis of trifluoromethylnaphthalenes
Mellor JM, et al.
Tetrahedron, 56(51), 10067-10074 (2000)
Novel deprotection of SEM ethers: a very mild and selective method using magnesium bromide
Vakalopoulos A and Hoffmann HMR
Organic Letters, 2(10), 1447-1450 (2000)
A facile and efficient one-pot synthesis of dihydropyrimidinones catalyzed by magnesium bromide under solvent-free conditions
Salehi H and Guo Q-X
Synthetic Communications, 34(1), 171-179 (2004)
Efficient Magnesium Bromide-Catalyzed One-pot Synthesis of Substituted 1, 2, 3, 4-Tetrahydropyrimidin-2-ones Under Solvent-free Conditions
Salehi H and Guo Q-X
Chin. J. Chem., 23(1), 91-97 (2005)
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