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About This Item
线性分子式:
CH3OCOCH2COOC(CH3)3
CAS号:
分子量:
174.19
Beilstein:
1772136
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
检测方案
95%
形式
liquid
杂质
5% dimethyl malonate
折射率
n20/D 1.415 (lit.)
bp
80 °C/11 mmHg (lit.)
密度
1.03 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)CC(=O)OC(C)(C)C
InChI
1S/C8H14O4/c1-8(2,3)12-7(10)5-6(9)11-4/h5H2,1-4H3
InChI key
XPSYZCWYRWHVCC-UHFFFAOYSA-N
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一般描述
tert-Butyl methyl malonate is an ester. Stereospecific Pd(O)-catalyzed addition of tert-butyl methyl malonate to allylic carbonates is reported.
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Bingli Yan et al.
The Journal of organic chemistry, 69(8), 2859-2862 (2004-04-13)
A combination of cross-metathesis and malonate addition was applied to a formal synthesis of the mammalian lignan enterolactone 5. The cross-metathesis of alkene 6 and phosphonate 3a gave the substituted allylic phosphonate 3d. The palladium-catalyzed addition of malonate 10d to
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