359661
H-Lys(Boc)-OH
≥95%, for peptide synthesis
别名:
Nε-Boc-L-赖氨酸
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关于此项目
线性分子式:
(CH3)3COCONH(CH2)4CH(NH2)COOH
化学文摘社编号:
分子量:
246.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
MDL number:
Beilstein/REAXYS Number:
2417626
产品名称
H-Lys(Boc)-OH, ≥95%
InChI
1S/C11H22N2O4/c1-11(2,3)17-10(16)13-7-5-4-6-8(12)9(14)15/h8H,4-7,12H2,1-3H3,(H,13,16)(H,14,15)/t8-/m0/s1
SMILES string
CC(C)(C)OC(=O)NCCCC[C@H](N)C(O)=O
InChI key
VVQIIIAZJXTLRE-QMMMGPOBSA-N
assay
≥95%
form
powder
optical activity
[α]20/D +18°, c = 1 in acetic acid
reaction suitability
reaction type: solution phase peptide synthesis
mp
250 °C (dec.) (lit.)
application(s)
peptide synthesis
storage temp.
2-8°C
Quality Level
General description
H-Lys(Boc)-OH又称为Nε-Boc-L-赖氨酸，常用于液相肽合成。
Application
H-Lys(Boc)-OH可制备五氟苯酯用于进一步合成β-肽。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
P J Thornalley et al.
The Biochemical journal, 344 Pt 1, 109-116 (1999-11-05)
The glycation of proteins by glucose has been linked to the development of diabetic complications and other diseases. Early glycation is thought to involve the reaction of glucose with N-terminal and lysyl side chain amino groups to form Schiff's base
C Toniolo et al.
International journal of peptide and protein research, 23(1), 47-54 (1984-01-01)
A solid-state and solution analysis of the homo-oligopeptides from epsilon-tert.-butyloxycarbonyl-L-lysine with p-oxymethylbenzylcholestan-3 beta-yl succinate as C-terminal group, using infrared absorption and circular dichroism, is described. The occurrence of intermolecular beta-structure is seen in the solid state and in solvents of
Ognyan K Argirov et al.
Biochimica et biophysica acta, 1620(1-3), 235-244 (2003-02-22)
Proteins are subject of posttranslational modification by sugars and their degradation products in vivo. The process is often referred as glycation. L-Dehydroascorbic acid (DHA), an oxidation product of L-ascorbic acid (vitamin C), is known as a potent glycation agent. A
Solution phase synthesis of beta-peptides using micro reactors
P Watts
Tetrahedron, 58, 5427-5439 (2002)
Shuqin Han et al.
Carbohydrate polymers, 90(2), 1061-1068 (2012-07-31)
A new third generation amphiphilic glycodendrimer was synthesized from a stearylamide lysine dendrimer by condensation of the oligosaccharide moiety. By stepwise condensation and deprotection of di-boc lysine from a core of stearyl amide lysine, a third-generation stearylamide lysine dendrimer was
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