所有图片(1)
别名:
(4R,5R)-2,2-二甲基-1,3-二氧戊环-4,5-二羧酸二甲酯, (4R,5R)-2,2-二甲基-1,3-二氧戊环-4-羧酸甲酯
经验公式（希尔记法）:
C9H14O6
CAS号:
分子量:
218.20
Beilstein:
15406
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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检测方案
97%
形式
liquid
旋光性
[α]20/D −54°, neat
折射率
n20/D 1.439 (lit.)
bp
150 °C/19 mmHg (lit.)
密度
1.190 g/mL at 20 °C (lit.)
SMILES字符串
COC(=O)[C@@H]1OC(C)(C)O[C@H]1C(=O)OC
InChI
1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m1/s1
InChI key
ROZOUYVVWUTPNG-PHDIDXHHSA-N
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应用
TADDOL 手性助剂、联吡啶配体和苏糖醇的有用结构单元。
(-)-Dimethyl 2,3-O-isopropylidene-L-tartrate may be used as a starting material in the total synthesis of (+)-migrastatin and also in the synthesis of a structural analog of S-ribosylhomocysteinase (LuxS), which acts as a potent competitive inhibitor against LuxS.
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves
法规信息
新产品
Design and synthesis of substrate and intermediate analogue inhibitors of S-ribosylhomocysteinase.
Shen G, et al.
Journal of Medicinal Chemistry, 49(10), 3003-3011 (2006)
Tetrahedron Letters, 31, 7179-7179 (1990)
Angewandte Chemie (International Edition in English), 30, 99-99 (1991)
Organic Syntheses, 68, 92-92 (1990)
The Journal of Organic Chemistry, 57, 6825-6825 (1992)
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