所有图片(1)
别名:
氘代四氯乙烷
线性分子式:
Cl2CDCDCl2
CAS号:
分子量:
169.86
Beilstein:
1699903
EC 号:
MDL编号:
UNSPSC代码:
12142201
PubChem化学物质编号:
NACRES:
NA.21
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同位素纯度
≥99.5 atom % D
质量水平
检测方案
≥99% (CP)
技术
NMR: suitable
折射率
n20/D 1.493 (lit.)
bp
145-146 °C/737 mmHg (lit.)
密度
1.62 g/mL at 25 °C (lit.)
应用
agriculture
environmental
质量偏移
M+2
SMILES字符串
[2H]C(Cl)(Cl)C([2H])(Cl)Cl
InChI
1S/C2H2Cl4/c3-1(4)2(5)6/h1-2H/i1D,2D
InChI key
QPFMBZIOSGYJDE-QDNHWIQGSA-N
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一般描述
1,1,2,2-四氯乙烷-d2是所有的氢原子被氘取代的1,1,2,2-四氯乙烷。它常被用作NMR溶剂。
应用
1,1,2,2-四氯乙烷-d2可用作以下反应的溶剂：
- 合成能源管理应用中的超级绝热材料环烯烃共聚物泡沫（COC） 。
- 在NMR测量中用于测定各种中间化合物。
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警示用语：
Danger
危险声明
危险分类
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Aquatic Chronic 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
美国出口管控1C298产品
非剧毒-急性毒性1
危险化学品
A E London et al.
Science advances, 5(5), eaav2336-eaav2336 (2019-05-30)
Interest in high-spin organic materials is driven by opportunities to enable far-reaching fundamental science and develop technologies that integrate light element spin, magnetic, and quantum functionalities. Although extensively studied, the intrinsic instability of these materials complicates synthesis and precludes an
Randi Zhang et al.
Dalton transactions (Cambridge, England : 2003), 48(47), 17488-17498 (2019-11-21)
Five structurally related bis(arylimino)pyridine-iron(ii) chloride complexes, [2-[CMeN{2,6-{(4-FC6H4)2CH}2-4-NO2}]-6-(CMeNAr)C5H3N]FeCl2 (Ar = 2,6-Me2C6H3Fe1, 2,6-Et2C6H3Fe2, 2,6-i-Pr2C6H3Fe3, 2,4,6-Me3C6H2Fe4, and 2,6-Et2-4-MeC6H2Fe5), incorporating one N-2,6-bis{di(4-fluorophenyl)methyl}-4-nitrophenyl group and one distinct N-aryl group, have been prepared in good yield through the interaction of the corresponding free ligands (L1-L5) with
Haobing Wang et al.
Journal of the American Chemical Society, 141(32), 12624-12633 (2019-07-26)
The precise control of regio- and stereochemistry in the cyclopolymerization of heteroatom-functionalized α,ω-dienes is of much interest and importance, but has remained a challenge to date. We report herein the regio-, diastereoselective and stereoregular cyclopolymerization of ether- and thioether-functionalized 1,6-heptadienes
Liwei Guo et al.
Dalton transactions (Cambridge, England : 2003), 48(17), 5604-5613 (2019-04-09)
A novel family of 2,6-bis[1-(p-dibenzocycloheptylarylimino)ethyl]pyridylcobalt dichlorides Co1-Co4 were synthesized and fully characterized by FT-IR, 1H NMR, and elemental analysis as well as X-ray diffraction analysis. The 1H NMR spectra of these paramagnetic cobalt complexes Co1-Co3 showed similar spectra with one
Emilie Steiner et al.
Magnetic resonance in chemistry : MRC, 53(8), 596-602 (2015-06-23)
Host-guest complexes between cryptophane-A analogue with butoxy groups (cryptophane-But) and chloromethanes (chloroform, dichloromethane) were investigated in the solid state by means of magic-angle spinning (13)C NMR spectroscopy. The separated local fields method with (13)C-(1)H dipolar recoupling was used to determine
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