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安全信息

357499

Sigma-Aldrich

氯化锡(IV) 溶液

1.0 M in heptane

别名:

四氯化锡, 氯化高锡

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About This Item

线性分子式:
SnCl4
CAS号:
7646-78-8
分子量:
260.52
MDL编号:
MFCD00011242
UNSPSC代码:
12352106
PubChem化学物质编号:
24861921
NACRES:
NA.22

表单

liquid

反应适用性

core: tin
reagent type: Lewis acid
reagent type: catalyst

浓度

1.0 M in heptane

密度

0.874 g/mL at 25 °C

SMILES字符串

Cl[Sn](Cl)(Cl)Cl

InChI

1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4

InChI key

HPGGPRDJHPYFRM-UHFFFAOYSA-J

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Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

靶器官

Central nervous system, Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

24.8 °F - closed cup

闪点(°C)

-4.0 °C - closed cup

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number
SHBN1813
SHBJ0636
SHBD2928V
SHBC2446
18496TM

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Abdul Hameed et al.
The Journal of organic chemistry, 73(20), 8045-8048 (2008-09-13)
A second generation formal synthesis of the alkaloid (-)-cephalotaxine has been achieved using an alkylidene carbene 1,5-CH insertion reaction to establish a key quaternary stereocenter. The carbene precursor was readily derived from L-proline, and the 1,5-CH insertion reaction was performed
Evangelina Repetto et al.
Bioorganic & medicinal chemistry, 17(7), 2703-2711 (2009-03-14)
Thiodisaccharides having beta-D-Galf or alpha-L-Araf units as non-reducing end have been synthesized by the SnCl(4)- or MoO(2)Cl(2)-promoted thioglycosylation of per-O-benzoyl-D-galactofuranose (1), its 1-O-acetyl analogue 4, or per-O-acetyl-alpha-L-arabinofuranose (16) with 6-thioglucose or 6-thiogalactose derivatives. After convenient removal of the protecting groups
Leo A Paquette et al.
The Journal of organic chemistry, 69(22), 7442-7447 (2004-10-23)
Tin tetrachloride-catalyzed glycosidation of persilylated nucleobases with acetate donor 6 in CH(2)Cl(2) solution followed by deprotection gave rise very predominantly to alpha-spironucleosides. These stereochemical assignments stem from the determination of NOE interactions and an X-ray crystallographic analysis of the latter
Glycosidation reactions of silyl ethers with conformationally inverted donors derived from glucuronic acid: stereoselective synthesis of glycosides and 2-deoxyglycosides.
Monika Poláková et al.
Angewandte Chemie (International ed. in English), 43(19), 2518-2521 (2004-05-06)
Yasuyuki Kita et al.
The Journal of organic chemistry, 71(14), 5191-5197 (2006-07-01)
The Lewis acid-promoted rearrangement of 2,2,3,3-tetrasubstituted 2,3-epoxy alcohols with several kinds of protecting groups was investigated. When SnCl4 is used as a Lewis acid, the reaction proceeds in a regio- and stereo-controlled manner to afford two types of carbonyl compounds
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