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检测方案
99%
形式
liquid
折射率
n20/D 1.453 (lit.)
bp
112 °C/740 mmHg (lit.)
密度
1.129 g/mL at 25 °C (lit.)
SMILES字符串
Cc1c(F)cccc1F
InChI
1S/C7H6F2/c1-5-6(8)3-2-4-7(5)9/h2-4H,1H3
InChI key
MZLSNIREOQCDED-UHFFFAOYSA-N
一般描述
2,6-Difluorotoluene reacts with chlorine to give 2,6-difluorobenzyl chloride, which gets converted to 2,6-difluorobenzaldehyde through Sommelet′s reaction. Six-fold potential for internal methyl rotation in first singlet excited state and cation ground state of 2,6-difluorotoluene has been determined.
应用
2,6-Difluorotoluene was used to generate jet-cooled 2,6-difluorobenzyl radical and to investigate its vibronically resolved emission spectra.
Observation of vibronic emission spectrum of the jet-cooled 2, 6-difluorobenzyl radical.
Lee SK and Baek DY.
The Journal of Physical Chemistry A, 104(22), 5219-5221 (2000)
Preparation of 2, 6-difluoro-n-alkylbenzenes from 1, 3-difluorobenzene Transformation of 2, 6-difluorotoluene to the corresponding benzaldehyde via benzyl chloride.
Malykhin EV and Shteingarts VD.
Journal of Fluorine Chemistry, 9(1), 19-20 (1998)
Methyl Group Internal Rotation in 2, 6-Difluorotoluene (S1) and 2, 6-Difluorotoluene+ (D0).
Walker RA, et al.
The Journal of Physical Chemistry, 99(33), 12422-12433 (1995)
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