346713
(1S,2S)-(+)-1,2-环己二胺
98%
别名:
(1S)-反式-1,2-二氨基环己烷, (1S)-反式-1,2-环己二胺
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关于此项目
线性分子式:
C6H10(NH2)2
化学文摘社编号:
分子量:
114.19
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2801645
Assay:
98%
Form:
solid
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1
SMILES string
N[C@H]1CCCC[C@@H]1N
InChI key
SSJXIUAHEKJCMH-WDSKDSINSA-N
assay
98%
form
solid
optical activity
[α]20/D +25°, c = 5 in 1 M HCl
optical purity
ee: 99% (GLC)
bp
104-110 °C/40 mmHg (lit.)
Quality Level
mp
40-43 °C (lit.)
Application
用于形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的手性 tropocoronand。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Design principles of chiral carbon nanodots help convey chirality from molecular to nanoscale level.
Luka Ðorđević et al.
Nature communications, 9(1), 3442-3442 (2018-08-26)
The chirality of (nano)structures is paramount in many phenomena, including biological processes, self-assembly, enantioselective reactions, and light or electron spin polarization. In the quest for new chiral materials, metallo-organic hybrids have been attractive candidates for exploiting the aforementioned scientific fields.
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
Jana Kasparkova et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(4), 1330-1341 (2007-11-21)
The different antitumor and other biological effects of the third-generation antitumor platinum drug oxaliplatin [(1R,2R-diamminocyclohexane)oxalatoplatinum(II)] in comparison with those of conventional cisplatin [cis-diamminedichloridoplatinum(II)] are often explained by the ability of oxaliplatin to form DNA adducts of different conformation and consequently
Cristina Nativi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(17), 4814-4820 (2011-03-10)
A new generation of chiral tripodal receptors for recognition of carbohydrates, featuring trans-1,2-diaminocyclohexane as a key structural element, and their recognition properties toward a set of glycosides of biologically relevant monosaccharides is described. The introduction of a chelating diamino unit
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