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质量水平
方案
98%
表单
solid
旋光性
[α]20/D +25°, c = 5 in 1 M HCl
光学纯度
ee: 99% (GLC)
沸点
104-110 °C/40 mmHg (lit.)
mp
40-43 °C (lit.)
SMILES字符串
N[C@H]1CCCC[C@@H]1N
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1
InChI key
SSJXIUAHEKJCMH-WDSKDSINSA-N
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应用
用于形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的手性 tropocoronand。
警示用语:
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Design principles of chiral carbon nanodots help convey chirality from molecular to nanoscale level.
Nature communications, 9(1), 3442-3442 (2018-08-26)
The chirality of (nano)structures is paramount in many phenomena, including biological processes, self-assembly, enantioselective reactions, and light or electron spin polarization. In the quest for new chiral materials, metallo-organic hybrids have been attractive candidates for exploiting the aforementioned scientific fields.
Tetrahedron Letters, 38, 7341-7341 (1997)
Aldrichimica Acta, 29, 59-59 (1996)
Journal of the American Chemical Society, 131(34), 12394-12405 (2009-08-27)
A series of Mn(IV)(salen)(L)(2) complexes bearing different external axial ligands (L = Cl, NO(3), N(3), and OCH(2)CF(3)) from chiral salen ligands with trans-cyclohexane-1,2-diamine as a chiral scaffold are synthesized, to gain insight into conformational properties of metal salen complexes. X-ray
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 74(3), 617-624 (2009-08-04)
In this study, the Schiff base ligand trans-N,N'-bis[(2,4-dichlorophenyl) methylidene] cyclohexane-1,2-diamine (L) and its copper(II), nickel(II) and palladium(II) transition metal complexes were prepared and characterized by the analytical and spectroscopic methods. The (1)H((13)C) NMR spectra of the ligand and its diamagnetic
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