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Merck
CN

346713

(1S,2S)-(+)-1,2-环己二胺

98%

别名:

(1S)-反式-1,2-二氨基环己烷, (1S)-反式-1,2-环己二胺

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关于此项目

线性分子式:
C6H10(NH2)2
化学文摘社编号:
分子量:
114.19
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2801645
Assay:
98%
Form:
solid
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InChI

1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1

SMILES string

N[C@H]1CCCC[C@@H]1N

InChI key

SSJXIUAHEKJCMH-WDSKDSINSA-N

assay

98%

form

solid

optical activity

[α]20/D +25°, c = 5 in 1 M HCl

optical purity

ee: 99% (GLC)

bp

104-110 °C/40 mmHg (lit.)

Quality Level

mp

40-43 °C (lit.)

Application

用于形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的手性 tropocoronand。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Luka Ðorđević et al.
Nature communications, 9(1), 3442-3442 (2018-08-26)
The chirality of (nano)structures is paramount in many phenomena, including biological processes, self-assembly, enantioselective reactions, and light or electron spin polarization. In the quest for new chiral materials, metallo-organic hybrids have been attractive candidates for exploiting the aforementioned scientific fields.
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
Kenji Yoshikawa et al.
Bioorganic & medicinal chemistry, 17(24), 8206-8220 (2009-11-04)
A series of cis-1,2-diaminocyclohexane derivatives were synthesized with the aim of optimizing previously disclosed factor Xa (fXa) inhibitors. The exploration of 5-6 fused rings as alternative S1 moieties resulted in two compounds which demonstrated improved solubility and reduced food effect
Farukh Arjmand et al.
Chirality, 23(3), 250-259 (2010-10-12)
A new chiral series of potential antitumor metal-based complexes 1-3(a and b) of L- and D-tryptophan have been synthesized and thoroughly characterized. Both enantiomers of 1-3 bind DNA noncovalently via phosphate interaction with slight preference of metal center for covalent

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