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![(R)-1,4-二氧杂螺[4.5]癸烷-2-甲醛](/deepweb/assets/sigmaaldrich/product/structures/115/595/dd44c9ec-b61d-4be8-b48a-32214fb60db8/640/dd44c9ec-b61d-4be8-b48a-32214fb60db8.png)
质量水平
方案
98%
表单
liquid
旋光性
[α]20/D +8.5°, c = 1.5 in acetone
折射率
n20/D 1.426 (lit.)
沸点
70-75 °C/10 mmHg (lit.)
密度
1.106 g/mL at 25 °C (lit.)
官能团
ester
ether
ketal
SMILES字符串
COC(=O)[C@H]1COC(C)(C)O1
InChI
1S/C7H12O4/c1-7(2)10-4-5(11-7)6(8)9-3/h5H,4H2,1-3H3/t5-/m1/s1
InChI key
DOWWCCDWPKGNGX-RXMQYKEDSA-N
应用
Methyl (R)-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxylate may be used as a starting material to synthesize (2R)-[1-2H2]-glycerol, a probe to study the stereochemistry of glycerol metabolism in Streptomyces cattleya. It may also be used to synthesize organic building blocks like (R)-2,3-dihydroxy-3-methylbutyl toluene-p-sulfonate and (2S,8R)-2-amino-8-[(R) 2,2-dimethyl-1,3-dioxolan-4-yl]-8-oxooctanoic acid.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
167.0 °F - closed cup
闪点(°C)
75 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Synthesis of 2-amino-8-oxodecanoic acids (Aodas) present in natural hystone deacetylase inhibitors.
Rodriquez M, et al.
The Journal of Organic Chemistry, 71(1) (2006)
Synthesis of (24 R)-11a-(4-carboxybutyryloxy)-24, 25-dihydroxyvitamin D 3: a novel haptenic derivative producing antibodies of high affinity for (24 R)-24, 25-dihydroxyvitamin D 3.
Kobayashi N, et al.
J. Chem. Soc., Perkin Trans., 3, 269-275 (1994)
Biosynthesis of fluoroacetate and 4-fluorothreonine by Streptomyces cattleya. The stereochemical processing of glycerol.
Nieschalk J, et al.
Chemical Communications (Cambridge, England), 8, 799-800 (1997)
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