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Merck
CN

345474

Sigma-Aldrich

三甲基硅醇锂

95%

别名:

三甲基硅烷醇 锂盐

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About This Item

线性分子式:
(CH3)3SiOLi
CAS号:
分子量:
96.13
Beilstein:
3686900
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

95%

表单

solid

SMILES字符串

[Li+].C[Si](C)(C)[O-]

InChI

1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChI key

OXOZHAWWRPCVGL-UHFFFAOYSA-N

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应用


  • Enhanced process and composition control for atomic layer deposition with lithium trimethylsilanolate: This study reports on the novel lithium precursor, lithium trimethylsilanolate (LiTMSO), for atomic layer deposition, comparing it with other lithium precursors for improved process and composition control (Ruud et al., 2017).

  • Trimethylsiloxy based metal complexes as electrolyte additives for high voltage application in lithium ion cells: The paper discusses the synthesis of lithium trimethylsilanolate and its use as an additive to enhance the performance of high voltage lithium ion cells (Imholt et al., 2017).

  • Application of trimethylsilanolate alkali salts in organic synthesis: This review covers various applications of lithium trimethylsilanolate in organic synthesis, highlighting its role in different reactions (Bürglová and Hlaváč, 2018).

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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D M Hui et al.
Clinica chimica acta; international journal of clinical chemistry, 302(1-2), 171-188 (2000-11-14)
We developed a new assay method for fluoride anion (F(-)) a specific metabolite of sarin. Trimethyifluorosilane (TMFS) was derivatized from F(-) with trimethylsilanol, and TMFS was detected with a GC-flame ionization detector (FID) and capillary column system. The linear range
Grzegorz Piechota et al.
Bioresource technology, 103(1), 16-20 (2011-10-29)
The removal and determination of trimethylsilanol (TMSOH) in landfill gas has been studied before and after the special E3000-ITC System. The system works according to principle of temperature swing. The performance of TMSOH and humidity removal was 20% and more
Igor S Ignatyev et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 60(5), 1169-1178 (2004-04-16)
The assignment of the SiOH group vibrations of trimethylsilanol, which is still controversial, is proposed. This assignment is based on theoretical B3LYP force field scaled using the constants of the (CH3)3Si group optimized to fit experimental vibrational frequencies of (CH3)3SiF
A Isquith et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 26(3), 263-266 (1988-03-01)
Six organosilicon compounds which had been found to have clastogenic activity in an in vitro battery of genotoxicity assays were evaluated in rat bone marrow cytogenetic assays for assessing clastogenicity in an in vivo system. None of the six compounds
Diane M Coe et al.
Organic & biomolecular chemistry, 1(7), 1106-1111 (2003-08-21)
A convenient and efficient method for the cleavage of 1,3-oxazolidin-5-ones and 1,3-oxazolidin-2-ones utilising potassium trimethylsilanolate in tetrahydrofuran is described. The benzyloxycarbonyl-protecting group is readily removed under the reaction conditions, whereas the N-benzoyl group is stable. A synthesis of (R)-salmeterol exploiting

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