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蒸汽压
20.89 psi ( 55 °C)
6.11 psi ( 20 °C)
质量水平
方案
96%
表单
liquid
自燃温度
743 °F
折射率
n20/D 1.421 (lit.)
沸点
44-46 °C (lit.)
mp
−135 °C (lit.)
溶解性
water: soluble 0.535 g/L at 25 °C
密度
0.771 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C1CC=CC1
InChI
1S/C5H8/c1-2-4-5-3-1/h1-2H,3-5H2
InChI key
LPIQUOYDBNQMRZ-UHFFFAOYSA-N
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一般描述
环戍烯是一种环烯烃。报道了新戊基膦配体催化的环戊烯 Heck 偶联反应。研究了基态氧原子与环戊烯反应的机理。报道了环戊烯均聚反应。报道了在不同的氧化钛催化剂上,环戊烯的光催化氧化。
应用
用环戊烯研究了金刚石 (001) 面与烯烃的 [2 + 2] 环加成反应。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
-29.9 °F - closed cup
闪点(°C)
-34.4 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
Stereospecific homopolymerization of cyclopentene.
Angewandte Chemie (International Edition in English), 3(11), 723-729 (1964)
Cycloaddition chemistry at surfaces: reaction of alkenes with the diamond (001)-2? 1 surface.
Journal of the American Chemical Society, 122(4), 732-733 (2000)
Journal of molecular graphics & modelling, 51, 184-192 (2014-06-18)
The reaction mechanism of the ground state oxygen atom O((3)P) with cyclopentene is investigated theoretically. The triplet and singlet potential energy surfaces are calculated at the CCSD(T)//MP2/6-311G(d,p) level and the minimum energy crossing points (MECPs) between the two surfaces are
Partial photocatalytic oxidation of cyclopentene over titanium (IV) oxide.
J. Mol. Catal. A: Chem., 242(1), 62-67 (2005)
The Journal of organic chemistry, 79(22), 10837-10848 (2014-10-22)
The use of neopentyl phosphine ligands was examined in the coupling of aryl bromides with alkenes. Di-tert-butylneopentylphosphine (DTBNpP) was found to promote Heck couplings with aryl bromides at ambient temperature. In the Heck coupling of cyclic alkenes, the degree of
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