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mp
160-164 °C (lit.)
SMILES字符串
OC(=O)c1c(Cl)cc(Cl)cc1Cl
InChI
1S/C7H3Cl3O2/c8-3-1-4(9)6(7(11)12)5(10)2-3/h1-2H,(H,11,12)
InChI key
RAFFVQBMVYYTQS-UHFFFAOYSA-N
一般描述
2,4,6-三氯苯甲酸的结构和氢键模式已经报道。
应用
2,4,6-三氯苯甲酸可用作微生物群落的唯一碳源和能量补充剂。它可用于合成 (+)-酒霉内酯,即大环内酯类抗生素酒霉素的糖苷配基。
作为反应物,参与以下反应:
烯烃的顺式双羟基化和环氧化的助催化剂
- 活性钠促进卤代苯甲酸的还原裂解
- 用作非甾体选择性糖皮质激素受体激动剂的芳基氨基吡唑苯甲酰胺合成
- 阻燃剂单体合成
- 用作抗真菌剂的 3,4,7-三取代香豆素合成
- 具有抗菌活性的山芬霉素类似物的固相合成
烯烃的顺式双羟基化和环氧化的助催化剂
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Journal of applied toxicology : JAT, 7(1), 67-70 (1987-02-01)
The acute rat oral LD50 of 2,4,6-Trichlorobenzyl chloride (TCBC) was determined to be 3075 mg/kg. When male and female rats were administered 1500 and 3000 ppm TCBC in the diet for 3 weeks, marked retardation in weight gain was observed.
2, 4, 6-Trichlorobenzoic acid: Structure and hydrogen-bonding pattern.
Acta Crystallographica Section C, Structural Chemistry, 52(7), 1801-1804 (1996)
Applied and environmental microbiology, 63(6), 2432-2438 (1997-06-01)
A microbial community was cultivated in flow cells with 2,4,6-trichlorobenzoic acid (2,4,6-TCB) as sole carbon and energy source and was examined with scanning confocal laser microscopy and fluorescent molecular probes. The biofilm community which developed under these conditions exhibited a
Organic & biomolecular chemistry, 7(21), 4458-4463 (2009-10-16)
Methynolide and 10-epi-methynolide were synthesized from the necessary segments, which were prepared by the addition of Grignard reagents to the corresponding alpha-alkoxyketones utilizing 1,2-stereochemical selection based on Cram chelation control. Ring-closing metathesis, as the key reaction, was carried out to
Nature, 585(7825), 420-425 (2020-09-04)
The opsin family of G-protein-coupled receptors are used as light detectors in animals. Opsin 5 (also known as neuropsin or OPN5) is a highly conserved opsin that is sensitive to visible violet light1,2. In mice, OPN5 is a known photoreceptor
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