344125
(R)-(+)-N,N-二甲基-1-二茂铁基乙胺
97%
别名:
(R)-(+)-[1-(二甲氨基)乙基]二茂铁
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关于此项目
经验公式（希尔记法）:
C14H19FeN
化学文摘社编号:
分子量:
257.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
InChI
1S/C9H14N.C5H5.Fe/c1-8(10(2)3)9-6-4-5-7-9;1-2-4-5-3-1;/h4-8H,1-3H3;1-5H;/t8-;;/m1../s1
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][CH]2)N(C)C
InChI key
ISOLNZQTVMCEOI-YCBDHFTFSA-N
assay
97%
form
liquid
optical activity
[α]20/D +13°, c = 1 in ethanol (5 h)
refractive index
n20/D 1.589 (lit.)
bp
120-121 °C/0.7 mmHg (lit.)
density
1.222 g/mL at 20 °C (lit.)
Application
用于手性烯丙醇、轴向手性丙二烯羧酸酯的制备，以及酮的铑(I)催化不对称氢化硅烷化反应的配体。
(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine may be used as a starting material to synthesize:
- chiral 1,2-disubstituted ferrocenyl amino alcohols
- ferrocene-based P-chiral phosphine ligands
- optically active α-ferrocenyl tertiary amines
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Stereoselective synthesis. VIII. Absolute configuration of a 1, 2-disubstituted ferrocene derivative with planar and central elements of chirality and the mechanism of the optically active. alpha.-ferrocenyl tertiary amines.
Battelle LF, et al.
Journal of the American Chemical Society, 95(2), 482-486 (1973)
Chiba, T. et al.
Tetrahedron Letters, 36, 1519-1519 (1995)
Chiral auxiliaries for asymmetric synthesis: enantioselective addition of dialkylzincs to aldehydes catalyzed by chiral 1, 2-disubstituted ferrocenyl amino alcohols.
Watanabe M, et al.
The Journal of Organic Chemistry, 56(6), 2218-2224 (1991)
Nishibayashi, Y. et al.
Tetrahedron Letters, 35, 3115-3115 (1994)
Nishibayashi, Y.et al.
Journal of the Chemical Society. Chemical Communications, 1375-1375 (1994)
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