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Merck
CN

343854

Sigma-Aldrich

甲醇-d3

99.8 atom % D

别名:

1,1,1-Trideuteromethanol, Methyl-d3 alcohol

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About This Item

线性分子式:
CD3OH
CAS号:
分子量:
35.06
Beilstein:
1732010
EC 号:
MDL编号:
UNSPSC代码:
12142201
PubChem化学物质编号:
NACRES:
NA.21

同位素纯度

99.8 atom % D

质量水平

检测方案

99% (CP)

形式

liquid

expl. lim.

5.5-36.5 % (lit.)

技术

NMR: suitable

杂质

≤0.05% water
water

折射率

n20/D 1.327 (lit.)

bp

65 °C (lit.)

密度

0.867 g/mL at 25 °C (lit.)

格式

neat

质量偏移

M+3

SMILES字符串

[2H]C([2H])([2H])O

InChI

1S/CH4O/c1-2/h2H,1H3/i1D3

InChI key

OKKJLVBELUTLKV-FIBGUPNXSA-N

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一般描述

甲醇-d 3 是一种氘代 NMR 溶剂,可用于基于 NMR 的研究和分析。

应用

甲醇-d 3 可与三甲基铝反应制备 [Al (CH 3 ) 2OCD 3 3 ,用于二烷基铝醇盐和三烷基铝醚络合物的光谱分析。

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警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

靶器官

Eyes,Central nervous system

WGK

WGK 2

闪点(°F)

51.8 °F

闪点(°C)

11 °C

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品
美国出口管控1C298产品

分析证书(COA)

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Władysław Wrzeszcz et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 188, 349-354 (2017-07-29)
Recently, we demonstrated the presence of microheterogeneity in binary mixtures of unlike alcohols. [RSC Adv. 2016, 6, 37195-37202] The aim of this work was examination if this phenomenon occurs also in the mixture of very similar alcohols like CH
Spectroscopic Studies of Dialkylaluminum Alkoxides and the Trialkyl-aluminum-Ether Complex. II. Assignments of Observed Frequencies
Tarao, R
Bulletin of the Chemical Society of Japan, 39(10), 2126-2132 (1966)
Paweł Tomza et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 197, 88-94 (2018-02-06)
Here we report ATR-IR spectroscopic study on the separation at a molecular level (microheterogeneity) and the degree of deviation of H2O/CH3OH and H2O/CD3OH mixtures from the ideal mixture. Of particular interest is the effect of isotopic substitution in methyl group
Thierry Jauffrais et al.
Marine drugs, 10(6), 1360-1382 (2012-07-24)
Azaspiracid (AZA) poisoning has been reported following consumption of contaminated shellfish, and is of human health concern. Hence, it is important to have sustainable amounts of the causative toxins available for toxicological studies and for instrument calibration in monitoring programs
Jason S Adams et al.
Science (New York, N.Y.), 371(6529), 626-632 (2021-02-06)
Solvent molecules influence the reactions of molecular hydrogen and oxygen on palladium nanoparticles. Organic solvents activate to form reactive surface intermediates that mediate oxygen reduction through pathways distinct from reactions in pure water. Kinetic measurements and ab initio quantum chemical

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