343803
甲醇-d4
≥99.8 atom % D, contains 0.03 % (v/v) TMS
别名:
全氘代甲醇, 四氘代甲醇
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关于此项目
线性分子式:
CD3OD
化学文摘社编号:
分子量:
36.07
UNSPSC Code:
12352104
NACRES:
NA.21
PubChem Substance ID:
EC Number:
212-378-6
Beilstein/REAXYS Number:
1733278
MDL number:
产品名称
甲醇-d4, ≥99.8 atom % D, contains 0.03 % (v/v) TMS
InChI key
OKKJLVBELUTLKV-MZCSYVLQSA-N
InChI
1S/CH4O/c1-2/h2H,1H3/i1D3,2D
SMILES string
[2H]OC([2H])([2H])[2H]
isotopic purity
≥99.8 atom % D
assay
≥99% (CP)
form
liquid
contains
0.03 % (v/v) TMS
expl. lim.
5.5-36.5 % (lit.)
technique(s)
NMR: suitable
impurities
≤0.025% water
water
refractive index
n20/D 1.326 (lit.)
bp
65.4 °C (lit.)
mp
-99 °C (lit.)
density
0.888 g/mL at 25 °C (lit.)
format
mixture
Quality Level
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Application
甲醇-d 4 可作为分析樟脑和正樟脑二甲基缩酮中甲氧基交换速率的溶剂。
General description
甲醇-d 4 是含 0.03% (v/v) TMS（三甲基硅烷）的氘代 NMR 溶剂。这在基于 NMR 的研究和分析中十分有用。
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
target_organs
Eyes,Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
49.5 °F - closed cup
flash_point_c
9.7 °C - closed cup
法规信息
危险化学品
美国出口管控产品
此项目有
Far-Infrared and Raman Spectra of Solid Methanol and Methanol-d4.
Durig JR, et al.
J. Chem. Phys. , 54(11), 4863-4870 (1971)
Antithrombotic Phenolics from the Stems of Parthenocissus tricuspidata Possess Anti-inflammatory Effect.
Nguyen PH, et al.
Bull. Korean Chem. Soc., 35(6), 1763-1763 (2014)
The Rates of Methoxyl Exchange of Camphor and Norcamphor Dimethyl Ketals in Methanol-d4.
Traylor TG and Perrin CL.
Journal of the American Chemical Society, 88(21), 4934-4942 (1966)
Cheng-Kun Lin et al.
Organic & biomolecular chemistry, 13(7), 2100-2107 (2014-12-20)
A straightforward synthesis of novel, 2-heterocyclyl polyhydroxylated pyrrolidines is described. Stereocontrolled additions of nucleophiles to cyclic nitrones generated the corresponding 2,3-trans adducts, allowing the synthesis of the corresponding pyrrolidines via key intermediates bearing an alkyne and a nitrile oxide. Three
Jon Kapla et al.
Physical chemistry chemical physics : PCCP, 17(34), 22438-22447 (2015-08-08)
The disaccharide trehalose (TRH) strongly affects the physical properties of lipid bilayers. We investigate interactions between lipid membranes formed by 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and TRH using NMR spectroscopy and molecular dynamics (MD) computer simulations. We compare dipolar couplings derived from DMPC/TRH
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