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Merck
CN

343412

Sigma-Aldrich

1,1-环丙烷二羧酸

97%

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线性分子式:
C3H4(CO2H)2
CAS号:
分子量:
130.10
Beilstein:
1864823
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

mp

134-136 °C (lit.)

溶解性

methanol: soluble 1 g/10 mL, clear, colorless

SMILES字符串

OC(=O)C1(CC1)C(O)=O

InChI

1S/C5H6O4/c6-3(7)5(1-2-5)4(8)9/h1-2H2,(H,6,7)(H,8,9)

InChI key

FDKLLWKMYAMLIF-UHFFFAOYSA-N

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一般描述

环丙烷-1,1-二羧酸是一种二羧酸。1-氨基环丙烷-1-羧酸氧化酶抑制剂环丙烷-1,1-二羧酸在圣女果中通过HPLC-电喷雾串联质谱法定量。环丙烷-1,1-二羧酸的晶体和分子结构 有酸的报道。

应用

以环丙烷-1,1-二羧酸为原料,合成了含噻二唑和 1,2,4-三唑基团的环丙烷二羧酸杂环衍生物。也用于制备螺-环丙基金属环。

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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The crystal and molecular structure of cyclopropane-1, 1-dicarboxylic acid.
Meester MAM, et al.
Acta Crystallographica Section B, Structural Science, 27(3), 630-634 (1971)
Tetrahedron, 45, 1219-1219 (1989)
Y H Dong et al.
Science in China. Series B, Chemistry, life sciences & earth sciences, 33(11), 1297-1303 (1990-11-01)
The crystal structures of [Pt(NH3)2CPrDCA].H2O (I), [Pt(CH3NH2)2CPrDCA] (II), and [Pt(dmbn) CPrDCA].2.5H2O (III) (where CPrDCA is 1,1-cyclopropanedicarboxylate; dmbn is 2,3-dimethyl-2,3-butyldiamine) are determined. Compound I crystallizes in the orthorhombic space group Pnma with the cell dimensions: a = 6.517(2), b = 9.709(3)
Michael B Johansen et al.
Organic letters, 10(16), 3497-3500 (2008-07-12)
Pyrrolo[1,2- a]indoles are conveniently prepared from tetrahydro-1,2-oxazines, which in turn are generated through the reaction of nitrones with 1,1-cyclopropanediesters. The synthetic route proves to be highly diastereoselective and provides access to the core of the recently discovered pyrrolo[1,2- a]indole natural
A Hussain K Sharba et al.
Molecules (Basel, Switzerland), 10(9), 1153-1160 (2007-11-17)
New heterocyclic derivatives of cyclopropane dicarboxylic acid comprising thiadiazole and 1,2,4-triazole moieties are reported. Reaction of 1,1-cyclopropane dicarboxylic acid (1) with thiosemicarbazide and phosphorous oxychloride resulted in 1,1-bis (2-amino-1,3,4-thiadiazol-5- yl)cyclopropane (2). Cyclopropane dicarboxylic acid thiosemicarbazide (6) was converted into 1,1-bis(3-thio-4H-1,2,4-triazol-5-yl)

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