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Merck
CN

343412

1,1-环丙烷二羧酸

97%

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线性分子式:
C3H4(CO2H)2
化学文摘社编号:
分子量:
130.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-917-2
Beilstein/REAXYS Number:
1864823
MDL number:
Assay:
97%
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InChI key

FDKLLWKMYAMLIF-UHFFFAOYSA-N

InChI

1S/C5H6O4/c6-3(7)5(1-2-5)4(8)9/h1-2H2,(H,6,7)(H,8,9)

SMILES string

OC(=O)C1(CC1)C(O)=O

assay

97%

mp

134-136 °C (lit.)

solubility

methanol: soluble 1 g/10 mL, clear, colorless

functional group

carboxylic acid

Quality Level

General description

环丙烷-1,1-二羧酸是一种二羧酸。1-氨基环丙烷-1-羧酸氧化酶抑制剂环丙烷-1,1-二羧酸在圣女果中通过HPLC-电喷雾串联质谱法定量。环丙烷-1,1-二羧酸的晶体和分子结构 有酸的报道。

Application

以环丙烷-1,1-二羧酸为原料,合成了含噻二唑和 1,2,4-三唑基团的环丙烷二羧酸杂环衍生物。也用于制备螺-环丙基金属环。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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分析证书(COA)

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The crystal and molecular structure of cyclopropane-1, 1-dicarboxylic acid.
Meester MAM, et al.
Acta Crystallographica Section B, Structural Science, 27(3), 630-634 (1971)
Tetrahedron, 45, 1219-1219 (1989)
A Hussain K Sharba et al.
Molecules (Basel, Switzerland), 10(9), 1153-1160 (2007-11-17)
New heterocyclic derivatives of cyclopropane dicarboxylic acid comprising thiadiazole and 1,2,4-triazole moieties are reported. Reaction of 1,1-cyclopropane dicarboxylic acid (1) with thiosemicarbazide and phosphorous oxychloride resulted in 1,1-bis (2-amino-1,3,4-thiadiazol-5- yl)cyclopropane (2). Cyclopropane dicarboxylic acid thiosemicarbazide (6) was converted into 1,1-bis(3-thio-4H-1,2,4-triazol-5-yl)
Yan-Biao Kang et al.
Organic & biomolecular chemistry, 4(2), 299-301 (2006-01-05)
A tandem ring-opening-cyclization reaction of cyclopropanes with imines in the presence of 5 mol% of scandium triflate was developed for the highly diastereoselective synthesis of multi-substituted pyrrolidines.
Konstantinos Petritis et al.
Phytochemical analysis : PCA, 14(6), 347-351 (2003-12-12)
Varying concentrations of cyclopropane-1,1-dicarboxylic acid (CDA), an inhibitor of 1-aminocyclopropane-1-carboxylic acid oxidase, added to the solid culture medium of tomato nodal shoot segments resulted in a reduction in the level of endogenous ethylene according to the concentration of inhibitor applied.

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