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质量水平
方案
99%
表单
powder
反应适用性
core: bismuth
reagent type: catalyst
mp
408 °C (lit.)
密度
5.78 g/mL at 25 °C (lit.)
SMILES字符串
I[Bi](I)I
InChI
1S/Bi.3HI/h;3*1H/q+3;;;/p-3
InChI key
KOECRLKKXSXCPB-UHFFFAOYSA-K
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应用
碘化铋(III)或三碘化铋无毒性，因此可作为环保催化剂使用。它可用作以下反应的催化剂：
- 水中的缩醛和缩酮的化学选择性脱保护反应。
- 硫脲和胺合成多取代胍的成胍反应。
- 羰基化合物的巯基化反应。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Bismuth (III) Halides and Sulfate as Highly Efficient Catalyst for the Sulfenylation of Carbonyl and Related Compounds1
Komatsu N, et al.
Synlett, 1995(09), 984-986 (1995)
Environmentally friendly organic synthesis using bismuth compounds: bismuth (III) iodide catalyzed deprotection of acetals in water
Bailey AD, et al.
Tetrahedron Letters, 49(4), 691-694 (2008)
The first bismuth (III)-catalyzed guanylation of thioureas
Cunha S and Rodrigues Jr MT
Tetrahedron Letters, 47(39), 6955-6956 (2006)
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
Jie Sun et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
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