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Merck
CN

341010

碘化铋(III)

99%, powder

别名:

三碘化铋, 三碘铋烷

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关于此项目

经验公式(希尔记法):
BiI3
化学文摘社编号:
分子量:
589.69
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
232-127-4
MDL number:
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产品名称

碘化铋(III), 99%

InChI key

KOECRLKKXSXCPB-UHFFFAOYSA-K

InChI

1S/Bi.3HI/h;3*1H/q+3;;;/p-3

SMILES string

I[Bi](I)I

assay

99%

form

powder

reaction suitability

core: bismuth
reagent type: catalyst

mp

408 °C (lit.)

density

5.78 g/mL at 25 °C (lit.)

Quality Level

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Application

碘化铋(III)或三碘化铋无毒性,因此可作为环保催化剂使用。它可用作以下反应的催化剂:
  • 水中的缩醛和缩酮的化学选择性脱保护反应。
  • 硫脲和胺合成多取代胍的成胍反应。
  • 羰基化合物的巯基化反应。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Bismuth (III) Halides and Sulfate as Highly Efficient Catalyst for the Sulfenylation of Carbonyl and Related Compounds1
Komatsu N, et al.
Synlett, 1995(09), 984-986 (1995)
The first bismuth (III)-catalyzed guanylation of thioureas
Cunha S and Rodrigues Jr MT
Tetrahedron Letters, 47(39), 6955-6956 (2006)
Environmentally friendly organic synthesis using bismuth compounds: bismuth (III) iodide catalyzed deprotection of acetals in water
Bailey AD, et al.
Tetrahedron Letters, 49(4), 691-694 (2008)
Jie Sun et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect

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