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Merck
CN

340928

Sigma-Aldrich

1,4-酐-赤藓糖醇

95%

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别名:
(3R,4S)-Tetrahydro-3,4-furandiol, Erythritol-1,4-anhydride, cis-3,4-Dihydroxytetrahydrofuran, cis-Tetrahydrofuran-3,4-diol, meso-3,4-Dihydroxytetrahydrofuran, rel-(3R,4S)-Tetrahydro-3,4-furandiol
经验公式(希尔记法):
C4H8O3
CAS号:
分子量:
104.10
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

形式

liquid

折射率

n20/D 1.477 (lit.)

密度

1.27 g/mL at 25 °C (lit.)

SMILES字符串

O[C@H]1COC[C@H]1O

InChI

1S/C4H8O3/c5-3-1-7-2-4(3)6/h3-6H,1-2H2/t3-,4+

InChI key

SSYDTHANSGMJTP-ZXZARUISSA-N

一般描述

1,4-脱水赤醇是一种环状邻位二醇。 1,4-脱水赤醇在氧化钨-钯催化剂上发生加氢脱氧反应,得到3-羟基四氢呋喃。

应用

1,4-脱水赤醇被用于合成缺少腺嘌呤成分的腺苷A的吡喃葡萄糖苷类似物的关键步骤。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves


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Yasushi Amada et al.
ChemSusChem, 7(8), 2185-2192 (2014-07-01)
Hydrodeoxygenation of cyclic vicinal diols such as 1,4-anhydroerythritol was conducted over catalysts containing both a noble metal and a group 5-7 transition-metal oxide. The combination of Pd and WOx allowed the removal of one of the two OH groups selectively.
Alex C Watanabe et al.
Environmental science & technology, 52(15), 8346-8354 (2018-06-29)
Laboratory and field measurements have demonstrated that isoprene epoxydiol (IEPOX) is the base component of a wide range of chemical species found in isoprene-derived secondary organic aerosol (SOA). To address newly raised questions concerning the chemical identities of IEPOX-derived SOA
Andrew M Riley et al.
Carbohydrate research, 337(12), 1067-1082 (2002-06-14)
Adenophostins A and B are naturally occurring glyconucleotides that interact potently with receptors for D-myo-inositol 1,4,5-trisphosphate, an important second messenger molecule in most cell types. Here we describe the design and synthesis of glucopyranoside-based analogues of adenophostin A lacking the
Aritomo Yamaguchi et al.
Physical chemistry chemical physics : PCCP, 19(4), 2714-2722 (2016-11-30)
The intramolecular dehydration of biomass-derived sugar alcohols d-sorbitol, d-mannitol, galactitol, xylitol, ribitol, l-arabitol, erythritol, l-threitol, and dl-threitol was investigated in high-temperature water at 523-573 K without the addition of any acid catalysts. d-Sorbitol and d-mannitol were dehydrated into isosorbide and

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