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50 EA
CN¥3,012.56
About This Item
线性分子式:
O2NC6H4CH(CH3)NH2 · HCl
CAS号:
分子量:
202.64
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
powder
旋光性
[α]25/D −6.5°, c = 1 in 0.05 M NaOH
mp
248-250 °C (lit.)
官能团
amine
nitro
SMILES字符串
Cl.C[C@H](N)c1ccc(cc1)[N+]([O-])=O
InChI
1S/C8H10N2O2.ClH/c1-6(9)7-2-4-8(5-3-7)10(11)12;/h2-6H,9H2,1H3;1H/t6-;/m0./s1
InChI key
CZQQGVFHLSBEDV-RGMNGODLSA-N
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此商品 | F2256 | F6760 | FBS25 |
|---|---|---|---|
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 500 |
| form powder | form powder | form powder | form powder |
| storage temp. room temp | storage temp. room temp | storage temp. −20°C | storage temp. −20°C |
| composition Dye content, 15% | composition Dye content, ~20% | composition - | composition - |
| λmax 284 nm | λmax - | λmax - | λmax - |
| ε (extinction coefficient) ≥3000 at 281-287 nm in water at 0.006 g/L | ε (extinction coefficient) - | ε (extinction coefficient) - | ε (extinction coefficient) - |
应用
(S)-α-Methyl-4-nitrobenzylamine hydrochloride can be used as:
- A fluorescence-quenching guest in the determination of chiral recognition capabilities of binaphthocrown ether and polythiophene complex.[1][2]
- A starting material in the synthesis of chiral cyclopalladated complexes with applications in the resolution of racemic compounds.[3]
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
The first orthopalladation of a primary nitrobenzylamine. Synthesis of chiral cyclopalladated complexes derived from (S)-α-methyl-4-nitrobenzylamine
Vicente J, et al.
J. Chem. Soc., Dalton Trans., 47(15), 2535-2539 (1995)
Polymer-based supramolecular sensing and application to chiral photochemistry
Fukuhara G
Polymer Journal, 47(10), 649-655 (2015)
Gaku Fukuhara et al.
Chemical communications (Cambridge, England), 48(11), 1641-1643 (2011-12-15)
Chiral recognition abilities of the title host for (R)- and (S)-α-methyl-4-nitrobenzylamine were examined in the ground and excited states to give a relative affinity (K(R)/K(S)) of 2.16 by spectral titration and a relative rate constant (k(R)/k(S)) of 2.23 by fluorescence
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