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方案
98%
mp
51-53 °C (lit.)
官能团
bromo
sulfone
SMILES字符串
BrCS(=O)(=O)c1ccccc1
InChI
1S/C7H7BrO2S/c8-6-11(9,10)7-4-2-1-3-5-7/h1-5H,6H2
InChI key
SKIMEKUYIQHJQV-UHFFFAOYSA-N
一般描述
Reaction of bromomethyl phenyl sulfone with potassium thiophenoxide in dimethyl formamide gave phenylthiomethyl phenyl sulfone. It undergoes disproportionation with KOH in DMSO at room temperature to yield methyl phenyl sulfone and dibromomethyl phenyl sulfone.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
从最新的版本中选择一种:
分析证书(COA)
Base-induced disproportionation of halomethyl phenyl sulfones to methyl and dihalomethyl phenyl sulfones.
The Journal of Organic Chemistry, 55(14), 4454-4456 (1990)
Nucleophilic displacements alpha to sulfonyl groupings.
The Journal of Organic Chemistry, 33(3), 1182-1185 (1968)
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