337528
烯丙基溴
reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer
别名:
3-溴-1-丙烯
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关于此项目
线性分子式:
CH2=CHCH2Br
化学文摘社编号:
分子量:
120.98
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-446-6
Beilstein/REAXYS Number:
605308
MDL number:
产品名称
烯丙基溴, reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
SMILES string
BrCC=C
grade
reagent grade
vapor density
4.2 (vs air)
assay
97%
form
liquid
autoignition temp.
554 °F
contains
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
refractive index
n20/D 1.469 (lit.)
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
density
1.398 g/mL at 25 °C (lit.)
functional group
alkyl halide
bromo
storage temp.
2-8°C
Quality Level
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Application
使用烯丙基溴：
- 通过Suzuki型偶联反应合成立体定向烯丙基化芳烃。
- 应用于醛和酮的Barbier型烯丙基反应。{17]
- 合成一个单体，1-1-（烯丙氧基）-4-硝基苯，同时合成纳米结构分子印迹聚合物，用于在生物和药物样品中选择性色氨酸的测定。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
Alizadeh T and Amjadi S
New. J. Chem., 41(11), 4493-4502 (2017)
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
Scrivanti A, et al.
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
Terra D Haddad et al.
The Journal of organic chemistry, 75(3), 642-649 (2009-12-24)
We report a simple, efficient, and general method for the indium-mediated enantioselective allylation of aromatic and aliphatic aldehydes and ketones under Barbier-type conditions in a one-pot synthesis affording the corresponding chiral alcohol products in very good yield (up to 99%)
Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones.
Jeremie J Miller et al.
Journal of the American Chemical Society, 129(10), 2752-2753 (2007-02-21)
Marcel S F Lie Ken Jie et al.
Lipids, 38(12), 1293-1297 (2004-02-12)
A methylene-interrupted C18 keto-acetylenic fatty ester (methyl 12-oxo-9-octadecynoate) was obtained from methyl ricinoleate by bromination-dehydrobromination followed by oxidation. Reaction of methyl 12-oxo-9-octadecynoate with bis(benzonitrile) palladium(II) chloride, allyl bromide, or methyl-allyl bromide furnished methyl 8-[5-hexyl-3-allyl-furan-2-yl]-octanoate (1, 56%) or methyl 8-15-hexyl-3-(2-methyl-allyl)-furan-2-yl]-octanoate (2
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