等级
reagent grade
质量水平
蒸汽密度
4.2 (vs air)
检测方案
97%
形式
liquid
自燃温度
554 °F
包含
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
折射率
n20/D 1.469 (lit.)
bp
70-71 °C (lit.)
mp
−119 °C (lit.)
密度
1.398 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
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应用
使用烯丙基溴：
- 通过Suzuki型偶联反应合成立体定向烯丙基化芳烃。
- 应用于醛和酮的Barbier型烯丙基反应。{17]
- 合成一个单体，1-1-（烯丙氧基）-4-硝基苯，同时合成纳米结构分子印迹聚合物，用于在生物和药物样品中选择性色氨酸的测定。
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
WGK
WGK 3
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Catalyst-Free Suzuki-Type Coupling of Allylic Bromides with Arylboronic Acids
Scrivanti A, et al.
European Journal of Organic Chemistry, 2012(2), 264-268 (2012)
A tryptophan assay based on the glassy carbon electrode modified with a nano-sized tryptophan-imprinted polymer and multi-walled carbon nanotubes
Alizadeh T and Amjadi S
New. J. Chem., 41(11), 4493-4502 (2017)
Kiew-Ching Lee et al.
Chemical communications (Cambridge, England), (40)(40), 4209-4211 (2006-10-13)
The total synthesis of natural (4R,5R)-antillatoxin and its analog (4S,5S)-antillatoxin has been achieved; the optically pure key intermediates were prepared from indium mediated allylation of either primary or secondary allylic bromide with aldehyde in aquoues media, followed by highly selective
Martín Fañanás-Mastral et al.
Chemical communications (Cambridge, England), 47(20), 5843-5845 (2011-04-20)
A stereoselective synthesis of 1,2-hydroxyalkyl moieties is described herein. These valuable building blocks are obtained with complete regiocontrol and excellent stereocontrol both for the syn or the anti products, by choosing the appropriate enantiomer of the ligand in a copper-catalyzed
Marcel S F Lie Ken Jie et al.
Lipids, 38(12), 1293-1297 (2004-02-12)
A methylene-interrupted C18 keto-acetylenic fatty ester (methyl 12-oxo-9-octadecynoate) was obtained from methyl ricinoleate by bromination-dehydrobromination followed by oxidation. Reaction of methyl 12-oxo-9-octadecynoate with bis(benzonitrile) palladium(II) chloride, allyl bromide, or methyl-allyl bromide furnished methyl 8-[5-hexyl-3-allyl-furan-2-yl]-octanoate (1, 56%) or methyl 8-15-hexyl-3-(2-methyl-allyl)-furan-2-yl]-octanoate (2
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