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Merck
CN

337021

Sigma-Aldrich

2-溴-3-甲基噻吩

95%

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经验公式(希尔记法):
C5H5BrS
CAS号:
分子量:
177.06
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

检测方案

95%

折射率

n20/D 1.572 (lit.)

bp

173-176 °C (lit.)

密度

1.572 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

Cc1ccsc1Br

InChI

1S/C5H5BrS/c1-4-2-3-7-5(4)6/h2-3H,1H3

InChI key

YYJBWYBULYUKMR-UHFFFAOYSA-N

一般描述

2-Bromo-3-methylthiophene is formed (approx. 90%) by bromination of 3-methyl thiophene with N-bromosuccinimide in the absence of benzoyl peroxide.

应用

2-Bromo-3-methylthiophene was used in the preparation of poly(3,3′′′-dimethyl-(2,2′:5′,2′:5′,2′′′)tetrathiophene)). It was also used in the preparation of 2-bromo-3-(bromomethyl)thiophene, lachrymatory compound.

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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The Effect of Benzoyl Peroxide on the Bromination of Methylthiophenes by N-Bromosuccinimide
Dittmer K, et al.
Journal of the American Chemical Society, 71(4), 1201-1204 (1949)
Regioregular poly (thiophene-3-alkanoic acid) s: water soluble conducting polymers suitable for chromatic chemosensing in solution and solid state.
Ewbank PC, et al.
Tetrahedron, 60(49), 11269-11275 (2004)
Structural studies of poly (dimethyl-tetrathiophene, an intermediate between poly (thiophene) and poly (3-methylthiophene).
Fell HJ, et al.
Synthetic Metals, 55(1), 420-425 (1993)

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