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应用
二氟化锡(SnF2)可用于:
- 形成SnF2–吡嗪复合物,在甲脒基碘化锡(FASnI3)钙钛矿太阳能电池(PSC)的制备中作为Sn4+抑制剂。
- 作为甘油缩酮化、Knoevenagel缩合和羟醛反应的催化剂。
- α, α-二溴苯乙酮和脂肪族、芳香族醛通过碳卤键的氧化加成合成α, β-环氧酮的反应。
- 立体控制[3 + 3] , [3 + 4], [3 + 5]环化反应。
警示用语:
Danger
危险分类
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2
储存分类代码
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Mingyu Hu et al.
Nature communications, 11(1), 151-151 (2020-01-11)
State-of-the-art halide perovskite solar cells have bandgaps larger than 1.45 eV, which restricts their potential for realizing the Shockley-Queisser limit. Previous search for low-bandgap (1.2 to 1.4 eV) halide perovskites has resulted in several candidates, but all are hybrid organic-inorganic compositions, raising potential concern regarding
Mukaiyama, T.; Yamaguchi, M.; Kato, J.
Synlett, 1505-1505 (1981)
Tin (II) Fluoride
Weigel LO
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 307(12), 828-835 (2001)
Shoda, S.; Mukaiyama, T.
Chemistry Letters (Jpn), 723-723 (1981)
Molander, G. A.; Shubert, D. C.
Journal of the American Chemical Society, 109, 576-576 (1987)
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Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
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