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方案
97%
表单
solid
mp
71-74 °C (lit.)
SMILES字符串
C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
InChI key
NDUYAGLANMHJHF-UHFFFAOYSA-N
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一般描述
Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.
应用
Allyltriphenylstannane can be used:
- As a reagent in the C-H phenylation of azoles catalyzed by palladium.
- As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)3.
- As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Allyltriphenylstannane
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Palladium-Catalyzed Direct Arylations of Azoles with Aryl Silicon and Tin Reagents
Han W, et al.
Chemistry?A European Journal , 17(25), 6904-6908 (2011)
Sc (OTf) 3-Catalyzed Conjugate Allylation of Alkylidene Meldrum′s Acids
Dumas AM and Fillion E
Organic Letters, 11(9), 1919-1922 (2009)
Total synthesis of (+)-ambruticin S: probing the pharmacophoric subunit
Hanessian S, et al.
The Journal of Organic Chemistry, 75(16), 5601-5618 (2010)
Journal of the American Chemical Society, 103, 1969-1969 (1981)
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