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Merck
CN

331929

Sigma-Aldrich

反,反-溴化金合欢酯

95%

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别名:
反,反-1-溴-3,7,11-三甲基-2,6,10-十二碳三烯
线性分子式:
(CH3)2C=CH[CH2CH2C(CH3)=CH]2CH2Br
CAS号:
分子量:
285.26
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

95%

形式

liquid

折射率

n20/D 1.509 (lit.)

bp

100-110 °C/15 mmHg (lit.)

密度

1.052 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

[H]\C(CBr)=C(\C)CC\C([H])=C(/C)CC\C=C(\C)C

InChI

1S/C15H25Br/c1-13(2)7-5-8-14(3)9-6-10-15(4)11-12-16/h7,9,11H,5-6,8,10,12H2,1-4H3/b14-9+,15-11+

InChI key

FOFMBFMTJFSEEY-YFVJMOTDSA-N

应用

法尼基溴用于制备:
  • S-反式,反 -法呢基-L-半胱氨酸甲酯,一种翻译后修饰氨基酸
  • 伞形花素,合成 (±)-法呢醇 A 和 (±)-法呢醇 C 的起始试剂
  • 异戊烯基化肽

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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M Liakopoulou-Kyriakides et al.
Amino acids, 2(3), 285-288 (1992-10-01)
S-trans, trans-farnesyl-L-cysteine methylester, a post translational modified amino acid, was synthesized from farnesyl bromide and L-cysteine methylester hydrochloride salt in the presence of triethylamine. Its purification as well as separation from the other isomers by HPLC on RP Vydac C4
Biogentic-type synthesis of (?)-farnesiferol A and (?)-farnesiferol C.
van Tamelen EE and Coates RM.
Chemical Communications (Cambridge, England), 13, 413-415 (1996)
O Kisselev et al.
The Journal of biological chemistry, 270(43), 25356-25358 (1995-10-27)
Post-translational prenylation of the carboxyl-terminal cysteine is a characteristic feature of the guanine nucleotide-binding protein (G protein) gamma subunits. Recent findings show that the farnesylated COOH-terminal tail of the gamma 1 subunit is a specific determinant of rhodopsin-transducin coupling. We

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