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质量水平
检测方案
98%
形式
liquid
折射率
n20/D 1.511 (lit.)
bp
82-85 °C/11 mmHg (lit.)
密度
1.25 g/mL at 25 °C (lit.)
SMILES字符串
Cn1cncc1Cl
InChI
1S/C4H5ClN2/c1-7-3-6-2-4(7)5/h2-3H,1H3
InChI key
NYDGOZPYEABERA-UHFFFAOYSA-N
一般描述
5-Chloro-1-methylimidazole is a 5-halo-1-methylimidazole. It participates in electron-rich iron(III) porphyrin complex catalyzed epoxidation of olefins.
应用
5-Chloro-1-methylimidazole was used in synthesis of C-5 functionalized N-methylated imidazoles.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
204.8 °F
闪点(°C)
96 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
An efficient route to 5-iodo-1-methylimidazole: synthesis of xestomanzamine A.
Panosyan FB and Still IWJ.
Canadian Journal of Chemistry, 79(7), 1110-1114 (2001)
W Nam et al.
Journal of inorganic biochemistry, 80(3-4), 219-225 (2000-09-23)
An electron-rich iron(III) porphyrin complex (meso-tetramesitylporphinato)iron(III) chloride [Fe(TMP)Cl], was found to catalyze the epoxidation of olefins by aqueous 30% H2O2 when the reaction was carried out in the presence of 5-chloro-1-methylimidazole (5-Cl-1-Melm) in aprotic solvent. Epoxides were the predominant products
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