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Merck
CN

32851

Sigma-Aldrich

反-1,4-二氨基环己烷

≥98.0% (GC)

别名:

反式-1,4-环己二胺

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About This Item

线性分子式:
C6H10(NH2)2
CAS号:
分子量:
114.19
Beilstein:
2801657
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

18 mmHg ( 87.2 °C)

检测方案

≥98.0% (GC)

自燃温度

680 °F

expl. lim.

6 %

bp

197 °C (lit.)

mp

68-72 °C (lit.)

SMILES字符串

N[C@H]1CC[C@H](N)CC1

InChI

1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-

InChI key

VKIRRGRTJUUZHS-IZLXSQMJSA-N

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应用

反式-1,4-二氨基环己烷可用于制备全脂族聚酰亚胺。 它被用作新型二维层状磷酸锌合成中的结构导向剂。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Skin Corr. 1B

WGK

WGK 2

闪点(°F)

159.8 °F

闪点(°C)

71 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Mohammad S Ali et al.
Journal of inorganic biochemistry, 96(4), 452-456 (2003-09-19)
A series of new platinum(II) and platinum(IV) adducts of type [P(II)(cis-1,4-DACH)LCl]NO(3,) where cis-1,4-DACH=cis-1,4-diaminocyclohexane, and L=9-ethylguanine, 1-methylcytosine, adenine, adenosine, cytosine, cytidine, guanine, and [Pt(IV)(cis-1,4-DACH)Ltrans-(X)(2)Cl]NO(3), (where Y=hydroxo or acetato), were synthesized and characterized by elemental analysis, infrared spectroscopy, and 1H and 195Pt
Shalini Balakrishnan et al.
The Journal of organic chemistry, 72(25), 9834-9837 (2007-11-06)
To introduce chirality and functional groups adjacent to guanidiniums to modulate specificity and affinity in recognition, N,N'-bis(Boc)-alpha-guanidino acids were synthesized from alpha-amino acid methyl esters. Protected alpha-guanidino acids coupled to cyclohexylamine and trans-1,4-diaminocyclohexane in good yield and with retention of
Han Wang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(42), e2003098-e2003098 (2020-10-01)
The crystalline orientation and phase distribution are two important parameters for high-performance 2D perovskite solar cells. Therefore, it is essential to understand how the structure of spacer ligands influences the orientation and phase distribution of resulting 2D perovskite films. In
F Vianello et al.
Protein expression and purification, 15(2), 196-201 (1999-03-02)
A novel, simple, and rapid procedure for the purification of pea seedling amine oxidase is reported. The crude enzyme, obtained by ammonium sulfate fractionation, was purified in two steps: the first one by anion-exchange chromatography and the second one by
Jana Kasparkova et al.
Biochemical pharmacology, 79(4), 552-564 (2009-09-29)
Earlier studies have described promising antitumor activity of a large-ring chelate complex [PtCl(2)(cis-1,4-DACH)] (DACH=diaminocyclohexane). Encouraging antitumor activity of this analogue of cisplatin prompted us to perform studies focused on the mechanistic basis of pharmacological effects of this complex. Four early

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