所有图片(2)
别名:
五羰基溴铼(I), 溴代五羰基铼
线性分子式:
Re(CO)5Br
CAS号:
分子量:
406.16
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
检测方案
98%
反应适用性
core: rhenium
reagent type: catalyst
SMILES字符串
Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key
NWJBOTGGBYFKEJ-UHFFFAOYSA-M
应用
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物，也可用于制备 [3]-二茂铁吩络合物。
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物。
铼-多吡啶络合物的原料，这种络合物在催化和太阳能转化中具有应用前景。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Jia-Li Jiang et al.
The Journal of organic chemistry, 70(1), 381-383 (2004-12-31)
In the presence of a catalytic amount of Re(CO)(5)Br, the coupling of epoxides with supercritical CO(2) without an organic solvent at 110 degrees C has afforded cyclic carbonates in good to excellent yields.
Ruimao Hua et al.
The Journal of organic chemistry, 69(17), 5782-5784 (2004-08-17)
The addition of carboxylic acids to terminal alkynes is efficiently catalyzed by the early transition-metal complex Re(CO)5Br in toluene or n-heptane at 110 degrees C in an air atmosphere, affording the anti-Markovnikov adducts in good yields with high selectivity. In
Nishiyama, Y.; Kakushou, F. et al.
Bulletin of the Chemical Society of Japan, 73, 2779-2779 (2000)
Inorganic Chemistry, 29, 2909-2909 (1990)
Tomás F Beltrán et al.
Dalton transactions (Cambridge, England : 2003), 46(28), 9036-9048 (2017-07-01)
The superbulky N-heterocyclic carbenes (NHCs) 2,6-bis(diphenylmethyl)-4-methylimidazol-2-ylidene (IDip*Me) and its 4-methoxy analogue (IDip*OMe) reacted instantaneously with carbon disulfide to afford the corresponding imidazolium-2-dithiocarboxylate zwitterions in high yields. These new dithiolate ligands were fully characterized and their coordination chemistry toward common Re(i)
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