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CN
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326755

Sigma-Aldrich

乙酸铜

greener alternative

98%

别名:

醋酸铜

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About This Item

线性分子式:
Cu(CO2CH3)2
CAS号:
142-71-2
分子量:
181.63
Beilstein:
3595638
EC 号:
205-553-3
MDL编号:
MFCD00008690
UNSPSC代码:
12352302
PubChem化学物质编号:
24859620
NACRES:
NA.22
方案:
98%
表单:
powder or crystals

蒸汽密度

6.9 (vs air)

质量水平

200

方案

98%

表单

powder or crystals

反应适用性

reaction type: click chemistry

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

环保替代产品分类

, Aligned

SMILES字符串

CC(=O)O[Cu]OC(C)=O

InChI

1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

OPQARKPSCNTWTJ-UHFFFAOYSA-L

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相关类别

一般描述

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处获取更多信息。

乙酸铜又名醋酸铜，在绿色化学领域，可用作多种过程的催化剂。尤其在交叉偶联反应中可促进碳-碳键或碳-杂原子键形成，而无需添加有害试剂或溶剂。

应用

氢气还原胺化反应合成胺这种绿色方法的催化剂。

使用环保的分子氢完成铜催化的芳酮和脂酮与苯胺的还原胺化反应

醋酸铜用作催化剂：
  • 用于α-氨基酯和对甲基苯硼酸经交叉偶联反应N-芳基化为双芳基
  • 用于取代异噁唑衍生物的合成

警示用语：

Danger

危险声明

H302,H314,H410

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

does not flash

闪点(°C)

does not flash

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000425998
0000425998
BCCM7903
0000407454
0000407455

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N-Arylation of ?-aminoesters with p-tolylboronic acid promoted by copper (II) acetate
PYS Lam, et al.
Tetrahedron Letters, 44, 1691-1694 (2003)
An efficient synthesis of novel isoxazole bearing pyrazole derivatives via [3+ 2] heteroannulation using cupric acetate
B Audichya, et al.
Journal of Heterocyclic Chemistry, 59, 341-350 (2022)
Heather A Michaels et al.
Chemistry, an Asian journal, 6(10), 2825-2834 (2011-09-29)
Polytriazole ligands such as the widely used tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine (TBTA), are shown to assist copper(II) acetate-mediated azide-alkyne cycloaddition (AAC) reactions that involve nonchelating azides. Tris(2-{4-[(dimethylamino)methyl]-1H-1,2,3-traizol-1-yl}ethyl)amine (DTEA) outperforms TBTA in a number of reactions. The satisfactory solubility of DTEA in a wide
Anitha M Thomas et al.
Journal of controlled release : official journal of the Controlled Release Society, 150(2), 212-219 (2010-11-26)
5-Fluorouracil (5-FU) is a small, very membrane permeable drug that is poorly retained within the aqueous compartment of liposomal nanoparticles (LNP). To address this problem a novel method relying on formation of a ternary complex comprising copper, low molecular weight
Cinthia da S Lisboa et al.
The Journal of organic chemistry, 76(13), 5264-5273 (2011-05-25)
The oxidative addition of anilines (2) with 1,4-naphthoquinone (3) to give N-aryl-2-amino-1,4-naphthoquinones (1) was found to be catalyzed by copper(II) acetate. In the absence of the catalyst, the reactions are slower and give lower yields with the formation of many
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