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方案
97%
表单
liquid
旋光性
[α]25/D +7.3°, c = 2 in chloroform
折射率
n20/D 1.483 (lit.)
密度
1.461 g/mL at 25 °C (lit.)
官能团
bromo
hydroxyl
SMILES字符串
C[C@@H](CO)CBr
InChI
1S/C4H9BrO/c1-4(2-5)3-6/h4,6H,2-3H2,1H3/t4-/m1/s1
InChI key
KIBOHRIGZMLNNS-SCSAIBSYSA-N
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应用
(S)-(+)-3-Bromo-2-methyl-1-propanol is a precursor to synthesize the phase II mexiletine metabolite, (R)-mexiletine N-carbonyloxy-β-D-glucuronide. It can be used in the synthesis of (R)-(+)-muscopyridine, polycavernoside A and (+)-allopumiliotoxin 323B′. It can also be employed in building homochiral porous molecular networks.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
197.6 °F - closed cup
闪点(°C)
92 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Total synthesis of the marine toxin polycavernoside A via selective macrolactonization of a trihydroxy carboxylic acid.
White J d, et al.
Journal of the American Chemical Society, 123(35), 8593-8595 (2001)
A Catalytic Approach to (R)?(+)?Muscopyridine with Integrated ?Self?Clearance?.
Furstner A and Leitner A
Angewandte Chemie (International Edition in English), 42(3), 308-311 (2003)
First synthesis and full characterization of mexiletine N-carbonyloxy ?-D-glucuronide.
Cavalluzzi M M, et al.
Tetrahedron Letters, 51(40), 5265-5268 (2010)
The Synthesis of (+)?Allopumiliotoxin 323B?.
Tan CH and Holmes A B
Chemistry?A European Journal , 7(9), 1845-1854 (2001)
Control and induction of surface-confined homochiral porous molecular networks.
Tahara K, et al.
Nature Chemistry, 3(9), 714-719 (2011)
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