所有图片(2)
别名:
(2S)-3-Bromo-2-methyl-1-propanol, (S)-3-Bromo-2-methylpropan-1-ol, (S)-3-Hydroxy-2-methylpropyl bromide
线性分子式:
BrCH2CH(CH3)CH2OH
CAS号:
分子量:
153.02
Beilstein:
4738280
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
检测方案
97%
形式
liquid
旋光性
[α]25/D +7.3°, c = 2 in chloroform
折射率
n20/D 1.483 (lit.)
密度
1.461 g/mL at 25 °C (lit.)
SMILES字符串
C[C@@H](CO)CBr
InChI
1S/C4H9BrO/c1-4(2-5)3-6/h4,6H,2-3H2,1H3/t4-/m1/s1
InChI key
KIBOHRIGZMLNNS-SCSAIBSYSA-N
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应用
(S)-(+)-3-Bromo-2-methyl-1-propanol is a precursor to synthesize the phase II mexiletine metabolite, (R)-mexiletine N-carbonyloxy-β-D-glucuronide. It can be used in the synthesis of (R)-(+)-muscopyridine, polycavernoside A and (+)-allopumiliotoxin 323B′. It can also be employed in building homochiral porous molecular networks.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Total synthesis of the marine toxin polycavernoside A via selective macrolactonization of a trihydroxy carboxylic acid.
White J d, et al.
Journal of the American Chemical Society, 123(35), 8593-8595 (2001)
First synthesis and full characterization of mexiletine N-carbonyloxy ?-D-glucuronide.
Cavalluzzi M M, et al.
Tetrahedron Letters, 51(40), 5265-5268 (2010)
The Synthesis of (+)?Allopumiliotoxin 323B?.
Tan CH and Holmes A B
Chemistry?A European Journal , 7(9), 1845-1854 (2001)
Control and induction of surface-confined homochiral porous molecular networks.
Tahara K, et al.
Nature Chemistry, 3(9), 714-719 (2011)
A Catalytic Approach to (R)?(+)?Muscopyridine with Integrated ?Self?Clearance?.
Furstner A and Leitner A
Angewandte Chemie (International Edition in English), 42(3), 308-311 (2003)
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