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方案
≥95%
表单
liquid
折射率
n20/D 1.5479 (lit.)
沸点
88 °C/1.3 mmHg (lit.)
密度
1.055 g/mL at 25 °C (lit.)
官能团
nitrile
SMILES字符串
N#CC1Cc2ccccc12
InChI
1S/C9H7N/c10-6-8-5-7-3-1-2-4-9(7)8/h1-4,8H,5H2
InChI key
FJIDKRPZJBUHME-UHFFFAOYSA-N
一般描述
Enantiomeric resolution of 1-benzocyclobutenecarbonitrile by CHIRALPAK IA, CHIRALPAK IB and CHIRALPAK IC (new generation chiral stationary phases) by chromatography was reported.
应用
1-Benzocyclobutenecarbonitrile was used as precursors of R-cyano- or R-keto-substituted o-quinodimethanes.
警示用语:
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Journal of chromatography. A, 1191(1-2), 214-222 (2008-01-08)
CHIRALPAK IA, CHIRALPAK IB and CHIRALPAK IC are a new generation of chiral packing materials for resolution of enantiomers by chromatography. They are all prepared by chemical immobilisation of the respective polysaccharide derivatives onto a supporting silica matrix. The present
o-Quinodimethanes: Efficient Intermediates in Organic Synthesis.
Chemical reviews, 99(11), 3199-3246 (2001-12-26)
Nature, 626(8000), 874-880 (2024-02-01)
Stress response pathways detect and alleviate adverse conditions to safeguard cell and tissue homeostasis, yet their prolonged activation induces apoptosis and disrupts organismal health1-3. How stress responses are turned off at the right time and place remains poorly understood. Here
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