检测方案
≥96%
形式
liquid
包含
0.4% hydroquinone as stabilizer
折射率
n20/D 1.445 (lit.)
bp
115-116 °C (lit.)
密度
0.865 g/mL at 25 °C (lit.)
SMILES字符串
OC(C=C)C=C
InChI
1S/C5H8O/c1-3-5(6)4-2/h3-6H,1-2H2
InChI key
ICMWSAALRSINTC-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
应用
不对称环氧化反应的原料。
在合成氨基取代的二烯时用作底物,其中通过磺酰胺亲核试剂进行铋催化 SNi 醇置换。
天然产物合成中的有用结构单元。
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 3
WGK
WGK 3
闪点(°F)
89.6 °F
闪点(°C)
32 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chin. J. Chem., 9, 381-381 (1991)
Journal of the American Chemical Society, 125(48), 14702-14703 (2003-12-04)
The enantioselective total synthesis of the annonaceous acetogenin (-)-mucocin (1) was accomplished using a triply convergent 12-step sequence (longest linear sequence) in 13.6% overall yield. This represents the first application of the temporary silicon-tethered (TST) ring-closing metathesis (RCM) cross-coupling reaction
Tetrahedron Asymmetry, 4, 1533-1533 (1993)
The Journal of organic chemistry, 69(4), 1144-1150 (2004-02-14)
Intermolecular hydroacylation between salicylaldehydes 1, 26-40 and 1,4-penta- or 1,5-hexadienes 4-13 by Rh-catalyst proceeded under mild reaction conditions to give a mixture of iso- and normal-hydroacylated products 14-25, 41-55, and 57-60. In the hydroacylation reaction, chelation of both salicylaldehyde and
Chemical communications (Cambridge, England), (9), 1134-1135 (2004-04-30)
Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.
我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门