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Merck
CN

323446

Sigma-Aldrich

四硫钼酸铵

99.97% trace metals basis

别名:

四硫代钼酸二铵, 硫代钼酸铵

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About This Item

线性分子式:
(NH4)2MoS4
CAS号:
分子量:
260.28
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
方案:
99.97% trace metals basis
表单:
crystalline

质量水平

方案

99.97% trace metals basis

表单

crystalline

反应适用性

reagent type: catalyst
core: molybdenum

杂质

≤350.0 ppm Trace Metal Analysis

mp

>300 °C (lit.)

SMILES字符串

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

InChI key

PQNOIAHNKHBLRN-UHFFFAOYSA-P

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应用

氮丙啶开环形成硫化物及二硫化物。
这种过渡金属硫簇合物的经典结构单元最近被用于低温固态合成一系列新型异金属硫簇合物(通过 dppm(双二苯基膦甲烷)配体稳定化)。

生化/生理作用

作为体内螯合剂降低铜含量。四硫代钼酸盐可干扰血管生成并减慢肿瘤生长。其机理可能涉及 NF-κB 和下游细胞因子的抑制。

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Satoru Yamasaki et al.
The Journal of cell biology, 177(4), 637-645 (2007-05-16)
Zinc is an essential trace element required for enzymatic activity and for maintaining the conformation of many transcription factors; thus, zinc homeostasis is tightly regulated. Although zinc affects several signaling molecules and may act as a neurotransmitter, it remains unknown
George J Brewer
Current cancer drug targets, 5(3), 195-202 (2005-05-17)
Tetrathiomolybdate (TM) is a novel anticopper agent under development for use in Wilson's disease. It acts by forming a stable tripartite complex with serum albumin and copper, rendering the complexed copper unavailable for cellular uptake. TM is a very potent
Yu Lei et al.
Science advances, 6(32), eabc4250-eabc4250 (2020-08-22)
Two-dimensional transition metal dichalcogenides (TMDs) emerged as a promising platform to construct sensitive biosensors. We report an ultrasensitive electrochemical dopamine sensor based on manganese-doped MoS2 synthesized via a scalable two-step approach (with Mn ~2.15 atomic %). Selective dopamine detection is
Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.
Pengfei Cao et al.
Scientific reports, 7(1), 16048-16048 (2017-11-24)
Amorphous molybdenum sulfide/carbon black (MoS

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