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质量水平
方案
99%
沸点
264 °C (lit.)
mp
164-166 °C (lit.)
SMILES字符串
Cc1c(C)c(C)c(C)c(C)c1C
InChI
1S/C12H18/c1-7-8(2)10(4)12(6)11(5)9(7)3/h1-6H3
InChI key
YUWFEBAXEOLKSG-UHFFFAOYSA-N
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一般描述
Hexamethylbenzene, also known as Mellitene, is an arene ligand that is commonly used as a precursor in the synthesis of organometallic complex.
应用
- 姜黄素和双去甲氧基姜黄素代谢产物的Ru(II)-芳烃络合物：研究Ru(II)-芳烃络合物与姜黄素代谢物的结构和反应性，为涉及六甲基苯衍生物的药物开发和合成途径的潜在应用提供启示（Dyson et al., 2024）。
- 大气中OH自由基降解聚甲基取代苯的理论研究：对包括六甲基苯在内的多甲基取代苯与OH自由基的大气反应进行全面的计算分析，以了解其环境影响（Zhao et al., 2024）。
- 重新审核五棱锥形C(6)H(6)(2+)和C(6)(CH(3))(6)(2+)指示键：探索了指示形式的六甲基苯的独特键和结构特征，为其在各种电子条件下的化学行为提供了启示（Torres et al., 2023）。
- 萘二亚胺功能化半夹层Ru（II）络合物作为线粒体靶向抗癌和抗转移药物的研究：讨论了六甲基苯结构Ru（II）络合物的合成和生物学评价，旨在开发新的治疗剂（Yang et al., 2023）。
- 不同反应条件下有机化合物对镍合金碳侵蚀的比较研究：研究了包括六甲基苯在内的有机化合物对工业应用相关镍合金的磨损和腐蚀的影响（Volodin et al., 2022）。
Hexamethylbenzene is used as a reagent during the synthesis of ketodiepoxides via hydroxylation reactions.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Effects of Substituted Triarylphosphine Ligands on Electron Transfer in [(p-cymene) Ru] Complexes
Anthony M N, et al.
Organometallics (2024)
The pentagonal-pyramidal hexamethylbenzene dication: many shades of coordination chemistry at carbon
Johannes K EMN, et al.
Chemistry?A European Journal , 24, 12340-12345 (2018)
Applications of Rozen?s Reagent in Oxygen-Transfer and C--H Activation Reactions
Kuldeep S, et al.
Synthesis, 51, 371-383 (2019)
P D Gorycki et al.
Chemical research in toxicology, 7(6), 745-751 (1994-11-01)
Hexamethyl(Dewar benzene) (HMDB) was selected to probe the intermediacy of an alkene radical cation during cytochrome P450 (P450) catalyzed epoxidation. P450 catalyzed the allylic oxidation of HMDB exclusively; no rearranged products (indicative of a radical cation intermediate) nor epoxide was
Judith Schlagnitweit et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 207(1), 168-172 (2010-09-21)
We demonstrate that proton NMR noise signals, i.e. NMR spectra without excitation by radio frequency, can be obtained from solid samples. Experimental results are shown for static and magic-angle spinning conditions. In addition, a tuning procedure based on the probes'
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