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Merck
CN

318183

Sigma-Aldrich

硫酸甲酯 钠盐

别名:

甲基硫酸钠

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About This Item

线性分子式:
CH3OSO3Na
CAS号:
分子量:
134.09
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

表单

powder

质量水平

杂质

<3% methanol
<5% water

mp

210 °C (lit.)

SMILES字符串

[Na+].COS([O-])(=O)=O

InChI

1S/CH4O4S.Na/c1-5-6(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1

InChI key

DZXBHDRHRFLQCJ-UHFFFAOYSA-M

应用

参与的反应物或试剂:
  • 微乳液法制备混杂纳米材料片层结构的研究
  • 离子液体辐射分解产生自由基离子的 EPR 研究
  • 微细胞研究特别是 1-苯甲酰基-1,2,4-三唑类化合物的水解缓速作用和混合胶束的自组装/微结构
硫酸甲酯钠盐可用于合成:
  • 基于硫酸甲酯阴离子的1,3,4-三烷基-1,2,3-三唑离子液体,用于Morita–Baylis–Hillman反应。
  • 与酚反应合成苯甲醚。
  • 羟基苯胺喹啉类化合物,用作RET激酶抑制剂。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

The discovery of substituted 4-(3-hydroxyanilino)-quinolines as potent RET kinase inhibitors
Robinett R G, et al.
Bioorganic & Medicinal Chemistry Letters, 17(21), 5886-5893 (2007)
Synthesis of new triazolium-based ionic liquids and their use in the Morita-Baylis-Hillman reaction
F Alioune, et al.
Tetrahedron Letters, 56(36), 5128-5131 (2015)
Synthesis of anisole from phenol and sodium methyl sulfate, a byproduct from synthesis of medicine intermediates
Guoping W, et al.
Petrochemical Technology, 45(11), 1337-1337 (2016)
Antonio Arroyo et al.
The Journal of biological chemistry, 277(51), 49965-49975 (2002-10-12)
Resolution of inflammation requires clearance of activated neutrophils by phagocytes in a manner that protects adjacent tissues from injury. Mechanisms governing apoptosis and clearance of activated neutrophils from inflamed areas are still poorly understood. We used dimethylsulfoxide-differentiated HL-60 cells showing
Bindhu V Karanam et al.
Drug metabolism and disposition: the biological fate of chemicals, 32(10), 1061-1068 (2004-07-02)
MK-0767 [(+/-)-5-[(2,4-dioxothiazolidin-5-yl)methyl]-2-methoxy-N-[[(4-trifluoromethyl)phenyl]methyl]benzamide], a thiazolidinedione (TZD)-containing peroxisome proliferator-activated receptor agonist, is a rapidly interconverting racemate that possesses a chiral center at the five position of the TZD ring. M25 is a methyl sulfide metabolite generated from MK-0767 following CYP3A4-mediated TZD ring

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