所有图片(1)
别名:
MCMT, 三羰基（2-甲基环戊二烯基）锰, （甲基环戊二烯基）三羰基锰, MMT, NSC 22316, 乙基 MMT
线性分子式:
C5H4CH3Mn(CO)3
CAS号:
分子量:
218.09
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽密度
>1 (vs air)
质量水平
蒸汽压
0.05 mmHg ( 20 °C)
形式
liquid
反应适用性
core: manganese
reagent type: catalyst
折射率
n20/D 1.584 (lit.)
bp
232-233 °C (lit.)
mp
−1 °C (lit.)
密度
1.38 g/mL at 25 °C (lit.)
SMILES字符串
[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1
InChI
1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;
InChI key
LYHJNAIHGFWRKM-UHFFFAOYSA-N
一般描述
甲基环戊二烯基三羰基锰（MMT）通常用作汽油中的抗爆剂。它也可用作无铅汽油的添加剂。
应用
甲基环戊二烯基锰三羰基可用于掺杂 ZnSe 纳米晶体。
它也可作为反应物用于：
它也可作为反应物用于：
- Aldol 加成反应
- 用共轭联噻吩单元制备均-和异核混合双卡宾配合物
- 使用成形飞秒激光脉冲的分子碎裂
- 金属有机气相外延（MOVPE）制备 GaAs（001）上生长的 MnAs薄膜
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation
靶器官
Lungs
WGK
WGK 3
闪点(°F)
204.8 °F
闪点(°C)
96 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Magnetic properties of MnAs thin films grown on GaAs(001) by MOVPE
Sterbinsky, G. E.; et al.
Physica B: Condensed Matter, 388, 370-370 (2007)
Wissam Abdallah et al.
Nanomaterials (Basel, Switzerland), 9(1) (2018-12-28)
Nanoparticles based on cellulose nanocrystals (CNC) and montmorillonite clay (MMT) were prepared using spray freeze-drying. The nanoparticles were then used as reinforcement to prepare nanocomposites with poly(lactic acid) (PLA) as the polymer matrix. The effect of spray freeze-dried CNC (SFD-CNC)
Effect of different manganese precursors on the doping efficiency in ZnSe nanocrystals
Zu, L,; et al.
The Journal of Physical Chemistry C, 114, 21969-21969 (2010)
Shimon Unterman et al.
ACS nano, 11(3), 2598-2610 (2017-02-22)
Hydrogels are an attractive class of biomaterials for minimally invasive local drug delivery given their injectability, tunability, high water content, and biocompatibility. Broad applicability though is challenged: relatively modest mechanical properties restrict use to soft tissues, while flow properties necessary
Hicham Achebak et al.
PLoS medicine, 15(7), e1002617-e1002617 (2018-07-25)
Anthropogenic greenhouse gas emissions have increased summer temperatures in Spain by nearly one degree Celsius on average between 1980 and 2015. However, little is known about the extent to which the association between heat and human mortality has been modified.
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