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Merck
CN

31460

Sigma-Aldrich

双丙酮葡萄糖

purum, ≥98.0% (TLC)

别名:

乙酰丙酮-D-葡萄糖, 二丙酮-D-葡萄糖

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About This Item

经验公式(希尔记法):
C12H20O6
CAS号:
分子量:
260.28
Beilstein:
84386
EC 号:
MDL编号:
UNSPSC代码:
12352201
PubChem化学物质编号:
NACRES:
NA.22

等级

purum

质量水平

方案

≥98.0% (TLC)

旋光性

[α]20/D −11.5±1°, c = 5% in ethanol

mp

110-111 °C (lit.)

SMILES字符串

CC1(C)OC[C@@H](O1)[C@H]2O[C@@H]3OC(C)(C)O[C@@H]3[C@H]2O

InChI

1S/C12H20O6/c1-11(2)14-5-6(16-11)8-7(13)9-10(15-8)18-12(3,4)17-9/h6-10,13H,5H2,1-4H3/t6-,7+,8-,9-,10-/m1/s1

InChI key

KEJGAYKWRDILTF-JDDHQFAOSA-N

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其他说明

葡萄糖的重要保护衍生物;可直接利用 3-OH,可选择性裂解 5,6-O-异亚丙基保护;3-OH 的氧化还原反应会生成异构呋喃糖衍生物;综述

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Yoon-Suk Kang et al.
Infection and immunity, 87(8) (2019-06-05)
Brucella is an intracellular bacterial pathogen that causes chronic systemic infection in domesticated livestock and poses a zoonotic infectious risk to humans. The virulence of Brucella is critically dependent on its ability to replicate and survive within host macrophages. Brucella
S. Iacono et al.
Organic Syntheses, 64, 57-57 (1986)
Z Huang et al.
Methods in molecular biology (Clifton, N.J.), 20, 315-353 (1993-01-01)
Two sets of experimental protocols are given for the synthesis of 3',5'-bis-homodeoxyribonucleosides, building blocks for the synthesis of oligodeoxynucleotide analogs where the -O-PO2-O- groups are replaced by -CH2-S-CH2-, -CH2-SO-CH2-, and -CH2-SO2-CH2- units. Conditions are presented for joining these building blocks
A. Vasella et al.
Modern Synthetic Methods, 2, 173-173 (1980)
E White et al.
Biomedical mass spectrometry, 9(9), 395-405 (1982-09-01)
Two isotope dilution mass spectrometric methods have been developed for the determination of D-glucose in human serum. Each uses a uniformly labeled (13C)glucose as the internal standard. The first method involves conversion of glucose into 1,2:5,6-di-O-isopropylidene-alpha-D-glucofuranose and an extensive clean-up

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