310115
三氯化磷
99.999% trace metals basis
别名:
氯化磷(III)
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关于此项目
线性分子式:
PCl3
化学文摘社编号:
分子量:
137.33
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
231-749-3
Beilstein/REAXYS Number:
969177
MDL number:
Assay:
99.999% trace metals basis
Form:
liquid
产品名称
三氯化磷, 99.999% trace metals basis
InChI key
FAIAAWCVCHQXDN-UHFFFAOYSA-N
InChI
1S/Cl3P/c1-4(2)3
SMILES string
ClP(Cl)Cl
vapor density
4.75 (vs air)
vapor pressure
100 mmHg ( 20 °C)
125 mmHg ( 25 °C)
385 mmHg ( 55 °C)
assay
99.999% trace metals basis
form
liquid
refractive index
n20/D 1.5148 (lit.)
bp
74-78 °C (lit.)
mp
−112 °C (lit.)
density
1.574 g/mL at 20 °C (lit.)
Quality Level
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation
target_organs
Respiratory Tract
supp_hazards
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
[X-ray analysis of lung damage caused by PCl3 inhalation].
Chun-fang Li et al.
Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases, 23(4), 308-309 (2005-09-29)
S Wason et al.
The American journal of medicine, 77(6), 1039-1042 (1984-12-01)
A railroad accident in Somerville, Massachusetts, led to spillage of phosphorus trichloride liquid. Attempted clean-up with water led to the liberation of phosphorus trichloride, phosphoric acid, hydrochloric acid, and phosphorus oxides. Seventeen people exposed to this mixture were studied. Patients
Action of phosphorus pentachloride on p-sulphonamido benzoic acid.
A D KEMP
Nature, 159(4041), 509-509 (1947-04-12)
D Zicane et al.
International journal of peptide and protein research, 48(1), 56-58 (1996-07-01)
N-Formylpyroglutamic acid-7-amido-4-methylcoumarine and pyroglutamyl-pyroglutamic acid-7-amido-4-methylcoumarin are the major products in the synthesis of pyroglutamic acid-7-amido-4-methylcoumarin by phosphorus pentachloride in dimethylformamide and dicyclohexylcarbodiimide under pyridine activation.
Núria Mont et al.
Molecular diversity, 13(1), 39-45 (2008-11-28)
A protocol for the synthesis of N-substituted 2-hydro-4-amino-pyrido[2,3-d]pyrimidin-7(8H)-ones (11) is described. Thus, the formylation of a 2-aminopyridone 12 in 85% formic acid/Ac(2)O, proceeding via in situ cyclization to the intermediate formamide 13, affords the corresponding 2-hydro-4-oxo-pyridopyrimidine 14, which is converted
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