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Merck
CN

310115

三氯化磷

99.999% trace metals basis

别名:

氯化磷(III)

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关于此项目

线性分子式:
PCl3
化学文摘社编号:
分子量:
137.33
UNSPSC Code:
12352300
NACRES:
NA.23
PubChem Substance ID:
EC Number:
231-749-3
Beilstein/REAXYS Number:
969177
MDL number:
Assay:
99.999% trace metals basis
Form:
liquid
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InChI key

FAIAAWCVCHQXDN-UHFFFAOYSA-N

InChI

1S/Cl3P/c1-4(2)3

SMILES string

ClP(Cl)Cl

vapor density

4.75 (vs air)

vapor pressure

100 mmHg ( 20 °C), 125 mmHg ( 25 °C), 385 mmHg ( 55 °C)

assay

99.999% trace metals basis

form

liquid

refractive index

n20/D 1.5148 (lit.)

bp

74-78 °C (lit.)

mp

−112 °C (lit.)

density

1.574 g/mL at 20 °C (lit.)

Quality Level

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signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation

target_organs

Respiratory Tract

supp_hazards

存储类别

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A Eldad et al.
Burns : journal of the International Society for Burn Injuries, 18(4), 340-341 (1992-08-01)
A 51-year-old chemical engineer sustained phosphorous pentachloride partial skin thickness burns over 20 per cent of his body surface area. Although macroscopically and microscopically the wound seemed to be superficial, the course of clinical healing of this injury was very
L Yu et al.
Amino acids, 28(4), 369-372 (2005-05-13)
The reactions of phosphorus trichloride with various amino acids afford the pentacoordinated spirophosphoranes. The reaction procedures were traced by (31)P NMR spectra techniques. A new crystal structure of alanine derivative was characterized, which is a slightly distorted TBP structure. Besides
Petri A Turhanen et al.
Organic & biomolecular chemistry, 1(18), 3223-3226 (2003-10-07)
Methods for the preparation of mixed tetra-amide esters 1 and 2, the partial amide ester 3, and tri- and P,P-diamides 4 and 5 from monophosphorus spieces 12, 8 and 9, respectively, were developed. Compounds 8 and 9 were obtained from
Phosphorus trichloride-mediated and microwave-assisted synthesis of a small collection of amides bearing strong electron-withdrawing group substituted anilines.
Matteo Colombo et al.
Journal of combinatorial chemistry, 11(3), 335-337 (2009-03-31)
Action of phosphorus pentachloride on p-sulphonamido benzoic acid.
A D KEMP
Nature, 159(4041), 509-509 (1947-04-12)

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