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Merck
CN

306797

Sigma-Aldrich

(S)-(-)-2-氯丙酸

99%

别名:

(S)-(-)-2-Chloropropanoic acid, L-α-氯丙酸

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About This Item

线性分子式:
CH3CH(Cl)CO2H
CAS号:
分子量:
108.52
Beilstein:
1720257
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:

方案

99%

表单

liquid

旋光性

[α]25/D −14°, neat

折射率

n20/D 1.4347 (lit.)

沸点

77 °C/10 mmHg (lit.)

密度

1.249 g/mL at 25 °C (lit.)

SMILES字符串

C[C@H](Cl)C(O)=O

InChI

1S/C3H5ClO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m0/s1

InChI key

GAWAYYRQGQZKCR-REOHCLBHSA-N

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应用

(S)-(-)-2-氯丙酸可用于制备(S)-(-)-2-氯丙酰氯 和 DOTMA ([αR*(αR*,α′R*,α”R*,α”′R*)]-(α,α′,α”,α”′)-四甲基-1,4,7,10-四氮杂环十二烷-1,4,7,10-四乙酸)配体。

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 1

闪点(°F)

222.8 °F - closed cup

闪点(°C)

106 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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A new ytterbium chelate as contrast agent in chemical shift imaging and temperature sensitive probe for MR spectroscopy.
Aime S, et al.
Magnetic Resonance in Medicine : Official Journal of the Society of Magnetic Resonance in Medicine / Society of Magnetic Resonance in Medicine, 35(5), 648-651 (1996)
Synthesis of optically pure. alpha.-alkylated. alpha.-amino acids and a single-step method for enantiomeric excess determination.
Kruizinga WH, et al.
The Journal of Organic Chemistry, 53(8) (1988)
Atsushi Kurata et al.
Journal of bioscience and bioengineering, 105(4), 429-431 (2008-05-24)
(S)-2-Chloropropionate is a synthetic intermediate for phenoxypropionic acid herbicides. We constructed a system for asymmetric reduction of 2-chloroacrylate to produce (S)-2-chloropropionate with recombinant Escherichia coli cells producing 2-haloacrylate reductase from Burkholderia sp. WS and an NADPH regeneration system. The system
Timothy P Higgins et al.
Biodegradation, 16(5), 485-492 (2005-05-04)
We previously reported the presence of both haloalcohol and haloalkanoate dehalogenase activity in the Agrobacterium sp. strain NHG3. The versatile nature of the organism led us to further characterise the genetic basis of these dehalogenation activities. Cloning and sequencing of
Fanny Mochel et al.
Molecular genetics and metabolism, 84(4), 305-312 (2005-03-23)
A six-day-old girl was referred for severe hepatic failure, dehydratation, axial hypotonia, and both lactic acidosis and ketoacidosis. Biotin-unresponsive pyruvate carboxylase deficiency type B was diagnosed. Triheptanoin, an odd-carbon triglyceride, was administrated as a source for acetyl-CoA and anaplerotic propionyl-CoA.

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