303259
1-氯-3-甲基-2-丁烯
95%
别名:
γ,γ-二甲基烯丙基氯, 1,1-二甲基-3-氯-1-丙烯, 1-氯-3-甲基-2-丁烯, 2-甲基-4-氯-2-丁烯, 3,3-二甲基烯丙基氯, 3-甲基-2-丁烯基氯, 3-甲基巴豆基氯, 4-氯-2-甲基-2-丁烯
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关于此项目
线性分子式:
(CH3)2C=CHCH2Cl
化学文摘社编号:
分子量:
104.58
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
207-972-7
MDL number:
产品名称
1-氯-3-甲基-2-丁烯, 95%
InChI key
JKXQKGNGJVZKFA-UHFFFAOYSA-N
InChI
1S/C5H9Cl/c1-5(2)3-4-6/h3H,4H2,1-2H3
SMILES string
C\C(C)=C\CCl
assay
95%
form
liquid
refractive index
n20/D 1.4488 (lit.)
bp
58-59 °C/120 mmHg (lit.)
density
0.928 g/mL at 25 °C (lit.)
functional group
alkyl halide
chloro
storage temp.
2-8°C
Quality Level
Application
1-氯-3-甲基-2-丁烯被用于香叶醇的全合成。
General description
已经研究了臭氧与1-氯-3-甲基-2-丁烯的气相反应的动力学。 已经研究了1-氯-3-甲基-2-丁烯与碘化钾在丙酮中的反应，以及与乙醇钠在乙醇中的反应。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
55.4 °F - closed cup
flash_point_c
13 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Allylic Chlorides. VIII. 1-Chloro-3-methyl-2-butene.
Hatch LF and Gerhardt LS.
Journal of the American Chemical Society, 71(5), 1679-1680 (1949)
The influence of orbital asymmetry on the kinetics of the gas-phase reactions of ozone with unsaturated compounds.
Johnson D, et al.
Physical Chemistry Chemical Physics, 2(3), 323-328 (2000)
Allylic Rearrangement in the Reactions of 1-Chloro-3-methyl-2-butene; an Attempt at Total Synthesis of Geraniol.
Kwart H and Miller RK.
Journal of the American Chemical Society, 76(21), 5403-5405 (1954)
Viktor P Bogdanov et al.
Chemistry, an Asian journal, 15(11), 1701-1708 (2020-04-16)
Alkylation of homofullerene [6,6]-C60 (CF2 )2- dianion with the set of alkyl halides, RX, was established to demonstrate an effect of RX nature on the conversion, product composition, and regioselectivity. The respective C60 (CF2 )RH, C60 (CF2 )R2 and C60
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