所有图片(1)
别名:
γ,γ-Dimethylallyl chloride, 1,1-Dimethyl-3-chloro-1-propene, 1-Chloro-3-methyl-2-butene, 2-Methyl-4-chloro-2-butene, 3,3-Dimethylallyl chloride, 3-Methyl-2-butenyl chloride, 3-Methylcrotyl chloride, 4-Chloro-2-methyl-2-butene
线性分子式:
(CH3)2C=CHCH2Cl
CAS号:
分子量:
104.58
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
检测方案
95%
形式
liquid
折射率
n20/D 1.4488 (lit.)
bp
58-59 °C/120 mmHg (lit.)
密度
0.928 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C\C(C)=C\CCl
InChI
1S/C5H9Cl/c1-5(2)3-4-6/h3H,4H2,1-2H3
InChI key
JKXQKGNGJVZKFA-UHFFFAOYSA-N
一般描述
已经研究了臭氧与1-氯-3-甲基-2-丁烯的气相反应的动力学。 已经研究了1-氯-3-甲基-2-丁烯与碘化钾在丙酮中的反应，以及与乙醇钠在乙醇中的反应。
应用
1-氯-3-甲基-2-丁烯被用于香叶醇的全合成。
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
55.4 °F
闪点(°C)
13 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
The influence of orbital asymmetry on the kinetics of the gas-phase reactions of ozone with unsaturated compounds.
Johnson D, et al.
Physical Chemistry Chemical Physics, 2(3), 323-328 (2000)
Allylic Chlorides. VIII. 1-Chloro-3-methyl-2-butene.
Hatch LF and Gerhardt LS.
Journal of the American Chemical Society, 71(5), 1679-1680 (1949)
Allylic Rearrangement in the Reactions of 1-Chloro-3-methyl-2-butene; an Attempt at Total Synthesis of Geraniol.
Kwart H and Miller RK.
Journal of the American Chemical Society, 76(21), 5403-5405 (1954)
Viktor P Bogdanov et al.
Chemistry, an Asian journal, 15(11), 1701-1708 (2020-04-16)
Alkylation of homofullerene [6,6]-C60 (CF2 )2- dianion with the set of alkyl halides, RX, was established to demonstrate an effect of RX nature on the conversion, product composition, and regioselectivity. The respective C60 (CF2 )RH, C60 (CF2 )R2 and C60
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