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Merck
CN

303143

Sigma-Aldrich

3,6-二甲基-1,4-二氧杂环己烷-2,5-二酮

99%

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别名:
DL-丙交酯, rac-丙交酯, 丙交酯
经验公式(希尔记法):
C6H8O4
CAS号:
分子量:
144.13
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

形式

crystals

bp

142 °C/8 mmHg (lit.)

mp

116-119 °C

储存温度

2-8°C

SMILES字符串

CC1OC(=O)C(C)OC1=O

InChI

1S/C6H8O4/c1-3-5(7)10-4(2)6(8)9-3/h3-4H,1-2H3

InChI key

JJTUDXZGHPGLLC-UHFFFAOYSA-N

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一般描述

3,6-二甲基-1,4-二恶烷-2,5-二酮(或 rac-丙交酯),是D和L-丙交酯50:50的外消旋混合物。rac-丙交酯是一种衍生自乳酸的内酯,因其源自丰富的可再生资源而引起了学术界和商业应用的极大兴趣。通过使用各种金属或有机催化剂,rac-丙交酯可以通过开环聚合进行聚合,从而得到聚(D,L-丙交酯)。虽然所得聚合物通常是无定形的,但立体定向催化剂的使用可生成异顺性PLA,其表现出一定程度的结晶度。

应用

3,6-二甲基-1,4-二恶烷-2,5-二酮可用作反应物:
  • 合成聚乳酸和聚碳酸酯的多嵌段共聚物。
  • 通过氧化丙烯、丙交酯和邻苯二甲酸酐的铝催化聚合生成多嵌段聚酯。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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