所有图片(1)
About This Item
线性分子式:
(CH3)2C=CHCH2CH2C(CH3)=CHCH2Cl
CAS号:
分子量:
172.69
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
95%
形式
liquid
折射率
n20/D 1.4808 (lit.)
bp
102-104 °C/12 mmHg (lit.)
密度
0.931 g/mL at 25 °C (lit.)
SMILES字符串
C\C(C)=C\CC\C(C)=C\CCl
InChI
1S/C10H17Cl/c1-9(2)5-4-6-10(3)7-8-11/h5,7H,4,6,8H2,1-3H3/b10-7+
InChI key
WLAUCMCTKPXDIY-JXMROGBWSA-N
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一般描述
Geranyl chloride undergoes palladium-catalyzed cross-coupling reaction with aryl and alkenylgold(I) phosphanes to afford the α-substitution product.
应用
Geranyl chloride was used as starting reagent in the synthesis of:
- C25 compound moenocinol
- 2-methyl-6-geranylphenol
- manoalide and seco-manoalide analogs
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
194.0 °F
闪点(°C)
90 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
A synthesis of moenocinol from isoprenoid precursors.
Bottger D and Welzel P.
Tetrahedron Letters, 24(47), 5201-5204 (1983)
Preparation and oxidative polymerization of 2-methyl-6-geranylphenol.
Hyun SH, et al.
Polymer Bull., 18(4), 283-286 (1987)
Toward elucidation of the inhibition mechanism of phospholipase A< sub> 2</sub> by manoalide: selectively modified amino acid residues by manoalide analogues.
Katsumura S, et al.
Bioorganic & Medicinal Chemistry Letters, 2(10), 1267-1268 (1992)
Palladium-catalyzed cross-coupling reactions of organogold(I) phosphanes with allylic electrophiles.
Miguel Peña-López et al.
Organic & biomolecular chemistry, 10(8), 1686-1694 (2012-01-24)
Aryl and alkenylgold(I) phosphanes react regioselectively with allylic electrophiles such as cinnamyl and geranyl halides (bromide, chloride and acetates) under palladium catalysis in THF at 80 °C to afford the α-substitution product with moderate to high yields. When the reaction
Minju Lee et al.
Scientific reports, 8(1), 13945-13945 (2018-09-19)
We report a strategy for the human-like smelling of a rose scent utilizing olfactory receptor nanodisc (ND)-based bioelectronic nose devices. In this strategy, a floating electrode (FE)-based carbon nanotube (CNT) field effect transistor (FET) was functionalized with human olfactory receptor
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