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Merck
CN

302163

(R)-(-)-1-苯基-1,2-乙二醇

99%

别名:

(-)-苯乙二醇, (R)-(-)-苯基乙二醇

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关于此项目

线性分子式:
HOCH2CH(C6H5)OH
化学文摘社编号:
分子量:
138.16
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2355547
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产品名称

(R)-(-)-1-苯基-1,2-乙二醇, 99%

InChI

1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1

SMILES string

OC[C@H](O)c1ccccc1

InChI key

PWMWNFMRSKOCEY-QMMMGPOBSA-N

assay

99%

optical activity

[α]20/D −69°, c = 1 in chloroform

bp

272-274 °C (lit.)

mp

64-67 °C (lit.)

functional group

hydroxyl
phenyl

Quality Level

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Application

合成不对称氢化反应的手性膦催化剂时所用的中间体。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Journal of Organic Chemistry, 44, 1729-1729 (1979)
J. Chem. Soc. Perkin Trans. II, 489-489 (1982)
Qingsen Hu et al.
Bioresource technology, 101(21), 8461-8463 (2010-06-25)
In this study, a highly efficient process for Candida parapsilosis-catalyzed deracemization of racemic 1-phenyl-1,2-ethanediol (PED) was described, based on a resin-based in situ substrate feeding and product removal (ISSFPR) methodology. The resin H103 was selected and used to keep the
Jin-Zhao Wang et al.
Biomedical chromatography : BMC, 21(5), 497-501 (2007-03-16)
A simple HPLC method for the simultaneous determination of phenylglyoxylic acid (PGA), mandelic acid (MA), styrene glycol (SG) and hippuric acid (HA) in cell culture medium was developed. Analysis was performed on a C(18) column with a mobile phase composed
Rongzhen Zhang et al.
Applied biochemistry and biotechnology, 160(3), 868-878 (2009-02-12)
An R-specific carbonyl reductase from Candida parapsilosis (CprCR) catalyzes the transformation of (R)-1-phenyl-1,2-ethanediol from 2-hydroxyacetophenone. The gene rcr coding CprCR contains a few codons rarely used by Escherichia coli. In order to improve chiral alcohol production, three codon variants Delta24

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