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302163

(R)-(-)-1-苯基-1,2-乙二醇

Name: (<I>R</I>)-(-)-1-苯基-1,2-乙二醇
Brand: ALDRICH

99%

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别名:

(-)-苯乙二醇, (R)-(-)-苯基乙二醇

线性分子式:

HOCH₂CH(C₆H₅)OH

CAS号:

16355-00-3

分子量:

138.16

Beilstein:

2355547

MDL编号:

MFCD00064262

UNSPSC代码:

12352002

PubChem化学物质编号:

24858238

NACRES:

NA.22

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Sigma-Aldrich

302155

(S)-(+)-1-苯基-1,2-乙二醇

Sigma-Aldrich

P24055

1-苯基-1,2-乙二醇

Sigma-Aldrich

559296

2-苯基-1,3-丙二醇

Sigma-Aldrich

540242

(R)-(-)-1,2-丙二醇

Sigma-Aldrich

D136808

2,2-二甲氧基丙烷

Sigma-Aldrich

375721

2-甲基-1,3-丙二醇

Sigma-Aldrich

8.02936

2,2-Dimethoxypropane

Sigma-Aldrich

901233

(2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole

Sigma-Aldrich

540099

(R)-(+)-氧化苯乙烯

Sigma-Aldrich

213764

2-苯基-1,2-丙二醇

检测方案

99%

旋光性

[α]20/D −69°, c = 1 in chloroform

bp

272-274 °C (lit.)

mp

64-67 °C (lit.)

SMILES字符串

OC[C@H](O)c1ccccc1

InChI

1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1

InChI key

PWMWNFMRSKOCEY-QMMMGPOBSA-N

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应用

合成不对称氢化反应的手性膦催化剂时所用的中间体。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

分析证书(COA)

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J. Chem. Soc. Perkin Trans. II, 489-489 (1982)

The Journal of Organic Chemistry, 44, 1729-1729 (1979)

DNA single strand breaks induced by low levels of occupational exposure to styrene: the gap between standards and reality.

Magdy Y Shamy et al.

Journal of environmental pathology, toxicology and oncology : official organ of the International Society for Environmental Toxicology and Cancer, 21(1), 57-61 (2002-04-06)

Styrene is a known mutagen and suspected carcinogen, used in the reinforced plastic industry. This study aims to identify the occurrence of DNA single strand breaks (SSBs) in workers exposed to styrene levels far below the recommended standards. We compared

[Construction of an enzyme-coupled system consisting of (R)- and (S)-specific carbonyl reductases for one-step preparation of (S)-1-phenyl-1,2-ethanediol].

Rongzhen Zhang et al.

Wei sheng wu xue bao = Acta microbiologica Sinica, 49(2), 204-209 (2009-05-19)

To prepare (S)-1-phenyl-1,2-ethanediol by a one-step method, we constructed an enzyme coupled system consisting of (R)- and (S)-specific carbonyl reductases in Escherichia coli. The genes coding (R)- and (S)-specific carbonyl reductases from Candida parapsilosis were inserted into a co-expression vector

Enantioconvergent production of (R)-1-phenyl-1,2-ethanediol from styrene oxide by combining the Solanum tuberosum and an evolved Agrobacterium radiobacter AD1 epoxide hydrolases.

Li Cao et al.

Biotechnology and bioengineering, 94(3), 522-529 (2006-02-25)

Soluble epoxide hydrolase (EH) from the potato Solanum tuberosum and an evolved EH of the bacterium Agrobacterium radiobacter AD1, EchA-I219F, were purified for the enantioconvergent hydrolysis of racemic styrene oxide into the single product (R)-1-phenyl-1,2-ethanediol, which is an important intermediate

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(R)-(-)-1-苯基-1,2-乙二醇

99%

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属性

检测方案

旋光性

bp

mp

SMILES字符串

InChI

InChI key

相关类别

说明

应用

安全信息

WGK

闪点(°F)

闪点(°C)

个人防护装备

文件

分析证书(COA)

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