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Merck
CN

301779

Sigma-Aldrich

5-氯邻菲得啉

98%

别名:

5-Chloro-1,10-diazaphenanthrene, 5-Chloro-o-phenanthroline

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About This Item

经验公式(希尔记法):
C12H7ClN2
CAS号:
分子量:
214.65
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

mp

124-126 °C (lit.)

SMILES字符串

Clc1cc2cccnc2c3ncccc13

InChI

1S/C12H7ClN2/c13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12/h1-7H

InChI key

XDUUQOQFSWSZSM-UHFFFAOYSA-N

应用

5-Chloro-1,10-phenanthroline was used in preparation of:
  • 1,10-phenanthrolinium cation, new building block for the design of ionic liquid crystals
  • platinum(II)-based metallointercalators

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Thomas Cardinaels et al.
Langmuir : the ACS journal of surfaces and colloids, 27(5), 2036-2043 (2011-01-22)
The 1,10-phenanthrolinium cation is introduced as a new building block for the design of ionic liquid crystals. 1,10-Phenanthroline, 5-methyl-1,10-phenanthroline, 5-chloro-1,10-phenanthroline, and 4,7-diphenyl-1,10-phenanthroline were quaternized by reaction with 1,3-dibromopropane or 1,2-dibromoethane. The resulting cations were combined with dodecyl sulfate or dioctyl
Sharon Kemp et al.
Journal of inorganic biochemistry, 101(7), 1049-1058 (2007-06-05)
Fifteen platinum(II)-based metallointercalators have been synthesised that utilise substituted 1,10-phenanthroline (phen) ligands, including 5-chloro-1,10-phenanthroline (5-Cl-phen), 5-methyl-1,10-phenanthroline (5-CH3-phen), 5-amino-1,10-phenanthroline (5-NH2-phen), 5-nitro-1,10-phenanthroline (5-NO2-phen) and dipyrido[3,2-d:2',3'-f]quinoxaline (dpq), and achiral ethylenediamine (en) and the chiral ancillary ligands 1S,2S-diaminocyclohexane (S,S-dach) and 1R,2R-diaminocyclohexane (R,R-dach). Their cytotoxicity

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