所有图片(2)
别名:
β,β′-二溴异丁酸
线性分子式:
(BrCH2)2CHCO2H
CAS号:
分子量:
245.90
Beilstein:
1752505
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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检测方案
97%
mp
98-101 °C (lit.)
SMILES字符串
OC(=O)C(CBr)CBr
InChI
1S/C4H6Br2O2/c5-1-3(2-6)4(7)8/h3H,1-2H2,(H,7,8)
InChI key
QQZJWQCLWOQDQV-UHFFFAOYSA-N
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一般描述
3-Bromo-2-(bromomethyl)propionic acid reacts with alkaline arsenite to yield (RS)-3-arsono-2-(hydroxymethyl)propionic acid.
应用
3-Bromo-2-(bromomethyl)propionic acid was used in the synthesis of t-butyl 2-(phenylthiomethyl)propenoate, t-butyl and methyl 3-(phenylthio)-2-(phenylthiomethyl)propenoate and 3-(phenylthio)-2-(phenyl- sulfinylmethyl)propenoate.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Preparation of t-Butyl 2-(Phenylthiomethyl) propenoate, t-Butyl 3-(Phenylthio)-2-(phenylthiomethyl) propenoate and related compounds.
Haynes RK, et al.
Australian Journal of Chemistry, 37(7), 1571-1578 (1984)
S Chawla et al.
Journal of enzyme inhibition, 8(4), 255-259 (1995-01-01)
(RS)-3-Arsono-2-(hydroxymethyl)propionic acid was synthesized by the action of alkaline arsenite on 3-bromo-2-(bromomethyl)propionic acid. It is a substrate for yeast enolase (EC 4.2.1.11) with a Km of 6.5 mM (for 2-phospho-D-glycerate Km = 0.08 mM). The catalytic constant of the enzyme
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