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About This Item
经验公式（希尔记法）:
C6H12S3
CAS号:
分子量:
180.35
Beilstein:
1616445
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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应用
1,4,7-Trithiacyclononane (9S3) is a tridentate thioether ligand that can be used to prepare complexes with a wide variety of transition metal ions. These complexes often possess exceptional electronic and redox properties. 9S3 ligand reacts with palladium metal ion to form palladium(II) thioether complex, which is used as a catalyst in the C-H activation reactions. Manganese complex of 9S3 ligand is employed as a catalyst for the oxidation of olefins, alkanes, and alcohols.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
The novel mixed-valence, exchange-coupled, class III dimer [L 2 Fe 2 (?-OH) 3] 2+(L= N, N?, N ?-trimethyl-1, 4, 7-triazacyclononane)
Drueke S, et al.
Journal of the Chemical Society. Chemical Communications, 22(1), 59-62 (1989)
1, 4, 7-Trithiacyclononane, a novel tridentate thioether ligand, and the structure of its nickel (II), cobalt (II), and copper (II) complexes
Setzer WN, et al.
Inorganic Chemistry, 22(2), 266-271 (1983)
C-H Bond Activation by a Palladium (II) Thioether Complex: Formation of the Bis (nitromethanate) Complex [Pd (9S3)(CH2NO2) 2]
Lee JP, et al.
Organometallics, 31(18), 6505-6513 (2012)
Dinuclear manganese complexes containing chiral 1, 4, 7-triazacyclononane-derived ligands and their catalytic potential for the oxidation of olefins, alkanes, and alcohols
Romakh VB, et al.
Inorganic Chemistry, 46(4), 1315-1331 (2007)
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