所有图片(4)
About This Item
线性分子式:
(CF3COO)2Pd
CAS号:
分子量:
332.45
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
方案
97%
表单
solid
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation
mp
~220 °C
SMILES字符串
FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F
InChI
1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
InChI key
PBDBXAQKXCXZCJ-UHFFFAOYSA-L
正在寻找类似产品? 访问 产品对比指南
相关类别
一般描述
三氟乙酸钯是一种催化剂，用于Suzuki-Miyaura、Heck和Stille交叉偶联反应。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Joshua S Dickstein et al.
Organic letters, 9(13), 2441-2444 (2007-06-05)
A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields. The method was useful with complex functionalized substrates containing hindered carboxylic acids.
David R Stuart et al.
Science (New York, N.Y.), 316(5828), 1172-1175 (2007-05-26)
The industrially important coupling of aromatic compounds has generally required differential prefunctionalization of the arene coupling partners with a halide and an electropositive group. Here we report that palladium, in conjunction with a copper oxidant, can catalyze the cross-coupling of
John E Bercaw et al.
The Journal of organic chemistry, 73(21), 8654-8657 (2008-09-30)
Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics. One of the major drawbacks of the homogeneous system is the tendency of the palladium trifluoroacetate
Tetrahedron Letters, 25, 4187-4187 (1984)
Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides.
Richard I McDonald et al.
Angewandte Chemie (International ed. in English), 49(32), 5529-5532 (2010-06-29)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门