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Merck
CN

298425

Sigma-Aldrich

三丁基硼烷

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别名:
TBB, Tributylboron
线性分子式:
[CH3(CH2)3]3B
CAS号:
分子量:
182.15
EC 号:
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22

反应适用性

reagent type: reductant

bp

109 °C/20 mmHg (lit.)

密度

0.747 g/mL at 25 °C (lit.)

SMILES字符串

CCCCB(CCCC)CCCC

InChI

1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3

InChI key

CMHHITPYCHHOGT-UHFFFAOYSA-N

应用

Reactant for:
  • Addition reactions for synthesis of phenyltrialkylborate salts
  • Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
  • Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
  • Multicomponent C-alkylation reactions with aromatic aldimines
  • One-pot alkylation-boration and electrophilic substitution

包装

Supplied in a Sure/Pac cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.

Compatible with the following:
For instructions please refer to technical bulletin AL-136: The Aldrich Sure/Pac Cylinder System

法律信息

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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Tetrahedron Letters, 33, 3779-3779 (1992)
S M Moerlein et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 44(9), 1213-1218 (1993-09-01)
Because [15O]butanol is the radiopharmaceutical of choice for PET studies of cerebral perfusion and neurological activation, we have developed a microprocessor-controlled radiosynthetic system for the preparation of this radiotracer in up to ten batches at a time. An IBM-compatible minicomputer
The Journal of Organic Chemistry, 59, 5530-5530 (1994)
Tetrahedron Letters, 35, 7201-7201 (1994)
Daisuke Nakayama et al.
The journal of adhesive dentistry, 12(4), 305-310 (2010-02-17)
The purpose of the current study was to evaluate the effect of acidic primers on the bond strength and durability of an acrylic resin luting agent to zirconia. Disk specimens were fabricated from zirconia partially stabilized with yttrium oxide (Katana

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