298190
氯化铈(III)
AnhydroBeads™, −10 mesh, 99.9%
别名:
三氯化铈, 氯化亚铈
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关于此项目
经验公式（希尔记法）:
CeCl3
化学文摘社编号:
分子量:
246.48
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
等级
synthesis grade
质量水平
产品线
AnhydroBeads™
方案
99.9%
反应适用性
core: cerium
reagent type: catalyst
杂质
≤1500.0 ppm Trace Rare Earth Analysis
粒径
−10 mesh
mp
848 °C (lit.)
密度
3.97 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Ce](Cl)Cl
InChI
1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VYLVYHXQOHJDJL-UHFFFAOYSA-K
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应用
当加到腈羟醛反应中时，非对映异构选择性增强，从而提高 β-羟基腈的产率。
法律信息
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 2
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Yanfang Wu et al.
Chemosphere, 74(9), 1260-1265 (2008-12-17)
Using both histochemical and cytochemical methods, we investigated the effects of copper (Cu) on the production of hydrogen peroxide (H2O2) and superoxide anion (O2(.-)) in the leaves of the moss Plagiomnium cuspidatum. Cu treatment significantly increased the contents of total
Xiaoming Tao et al.
Organic letters, 15(1), 72-75 (2012-12-25)
Dynamic kinetic resolution of various α-amido-β-keto phosphonates via asymmetric hydrogenation proceeded efficiently to give the corresponding β-hydroxy-α-amido phosphonates in high diastereo- and enantioselectivities (up to 99:1 syn/anti, 99.8% ee). The addition of catalytic amounts of CeCl(3)·7H(2)O is necessary to achieve
Na Li et al.
Environmental toxicology, 28(6), 349-358 (2011-06-10)
To investigate the molecular mechanism of inflammatory response in the mouse liver caused by exposure to CeCl₃, we measured the liver indices, and cerium content, evaluated the liver histopathological section, detected serum biochemical parameters of liver function, and the immunoglobulin
Giuseppe Bartoli et al.
Organic & biomolecular chemistry, 8(15), 3509-3517 (2010-06-10)
The occurrence of unsaturated systems in natural products combined with the mildness and the wide range of applicability of CeCl(3) promoted methodologies suggest several potential future synthetic applications within the field of total synthesis of biologically active molecules. On this
Masami Kawagoe et al.
Journal of trace elements in medicine and biology : organ of the Society for Minerals and Trace Elements (GMS), 22(1), 59-65 (2008-03-06)
We evaluated tissue changes associated with cerium chloride administration via gavage to adult mice, via milk to neonatal mice and transplacentally to fetal mice. Change in adults consisted of extensive pulmonary hemorrhage, pulmonary venous congestion, thickened alveolar septae, hepatic necrosis
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