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质量水平
反应适用性
reagent type: reductant
浓度
5.0 M in 1 M NaOH
密度
1.083 g/mL at 25 °C
SMILES字符串
[Na+].[H][B-]([H])([H])C#N
InChI
1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1
InChI key
CVDUGUOQTVTBJH-UHFFFAOYSA-N
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一般描述
氰基硼氢化钠是一种选择性的温和还原剂，适用于多种官能团，如醛、酮、缩醛、环氧化物和亚胺。
应用
可作为如下反应的反应物：
- 将杂环醛直接转化为酯（氧化行为）
- 还原胺化反应
- 分子内还原环化反应
- 还原反应
- 作为双组元推进剂的自燃流体，制备基于二氰基硼酸盐的离子液体
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
补充剂危害
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
e-EROS Encyclopedia of Reagents for Organic Synthesis (2016)
Franklin Afinjuomo et al.
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The propensity of monocytes to migrate into sites of mycobacterium tuberculosis (TB) infection and then become infected themselves makes them potential targets for delivery of drugs intracellularly to the tubercle bacilli reservoir. Conventional TB drugs are less effective because of
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Bioorganic & medicinal chemistry letters, 13(16), 2633-2636 (2003-07-23)
We report here that unprotected carbohydrates (maltose, lactose, cellobiose, and maltoheptaose) can be attached to the aminoalkylated oligonucleotides under mild reductive-amination conditions (aqueous borate buffer, pH 8.0, NaBH(3)CN, 60 degrees C) without notable side reactions. Quadruplex-forming G-rich oligonucleotide, 5'-aminoalkyl d(TGGGGT)
Chika Wakita et al.
The Journal of biological chemistry, 284(42), 28810-28822 (2009-08-21)
4-Hydroxy-2-nonenal (HNE), a major racemic product of lipid peroxidation, preferentially reacts with cysteine residues to form a stable HNE-cysteine Michael addition adduct possessing three chiral centers. Here, to gain more insight into sulfhydryl modification by HNE, we characterized the stereochemical
Heather L Lord et al.
Journal of pharmaceutical and biomedical analysis, 44(2), 506-519 (2007-02-23)
Immunoaffinity solid phase microextraction (SPME) probes have been developed with antibodies specific for the benzodiazepine class of drugs, covalently immobilized to glass rods. This involved both purification of the polyclonal antibodies to isolate the drug-specific fraction, and optimization of the
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