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质量水平
反应适用性
reagent type: reductant
浓度
5.0 M in 1 M NaOH
密度
1.083 g/mL at 25 °C
SMILES字符串
[Na+].[H][B-]([H])([H])C#N
InChI
1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1
InChI key
CVDUGUOQTVTBJH-UHFFFAOYSA-N
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一般描述
氰基硼氢化钠是一种选择性的温和还原剂，适用于多种官能团，如醛、酮、缩醛、环氧化物和亚胺。
应用
可作为如下反应的反应物：
- 将杂环醛直接转化为酯（氧化行为）
- 还原胺化反应
- 分子内还原环化反应
- 还原反应
- 作为双组元推进剂的自燃流体，制备基于二氰基硼酸盐的离子液体
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
e-EROS Encyclopedia of Reagents for Organic Synthesis (2016)
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We report here that unprotected carbohydrates (maltose, lactose, cellobiose, and maltoheptaose) can be attached to the aminoalkylated oligonucleotides under mild reductive-amination conditions (aqueous borate buffer, pH 8.0, NaBH(3)CN, 60 degrees C) without notable side reactions. Quadruplex-forming G-rich oligonucleotide, 5'-aminoalkyl d(TGGGGT)
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Stable-isotope labeling coupled with liquid-phase separation and MS analysis is a powerful technique for comparative proteomics. We developed a dimethyl labeling strategy (Anal. Chem. 2003, 75, 6843-6852 and J. Proteome Res. 2005, 4, 101-108) to label peptide N-terminus and epsilon-amino
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